International audienceWe have re-investigated the synthesis and the crystal structure of the non-centrosymmetric phase Co6(OH)3(TeO3)4(OH) published by Perez et al. in 1975 and we have obtained by hydrothermal synthesis the hydrated phase Co6(OH)3(TeO3)4(OH)~0.9(H20). The crystal structure related to the Ellenbergerite mineral was determined using single-crystal X-ray diffraction data. The non-centrosymmetric hexagonal structure (P63mc; a = 13.1640(7) Å; c = 5.0321(6) Å) is based on [CoO6] octahedra and [TeO3] polyhedra which formed a tunnel framework with a formal charge 1+ balanced by one OH- group located in large tunnels. Compared to Co6(OH)3(TeO3)4(OH) case we succeeded in locating the hydrogen atoms of the OH- groups bound to the Co a...
The crystal structure and magnetic properties of Co(HPO3)⋅H2O have been determined. The solid crysta...
The crystal structure and magnetic properties of Co(HPO3)⋅H2O have been determined. The solid crysta...
International audienceThe magnetic properties of a novel cobalt-based hydrogen vanadate, Co-13.5(OH)...
Previously unknown Co2(TeO3)(OH)2 and Co15(TeO3)14(OH)2 were obtained under mild hydrothermal reacti...
New tellurite–sulfate compounds M<sub>2</sub>(TeO<sub>3</sub>)(SO<sub>4</sub>)·H<sub>2</sub>O (M = ...
International audienceThe new oxofluoride Co15F2(TeO3)14 has been prepared by optimized hydrothermal...
International audienceThe structures (nuclear and magnetic), magnetic properties (2-300 K, 1-104 bar...
International audienceThe new oxofluoride Co15F2(TeO3)14 has been prepared by optimized hydrothermal...
International audienceNew Ni3TeO6-type (NTO) and double perovskite (DPv) polymorphs of Co3TeO6 are s...
In this study, we measured the temperature-dependent magnetic susceptibility [chi(T)], ac magnetic s...
International audienceNew Ni3TeO6-type (NTO) and double perovskite (DPv) polymorphs of Co3TeO6 are s...
International audienceNew Ni3TeO6-type (NTO) and double perovskite (DPv) polymorphs of Co3TeO6 are s...
A new framework cobalt(II) hydroxyl phosphate, Co2PO4OH, was prepared by ionothermal synthesis using...
The synthesis, characterization, crystal structure, and magnetic properties of Co2(OH)2BDC and Co(H2...
A new framework cobalt(II) hydroxyl phosphate, Co2PO4OH, was prepared by ionothermal synthesis using...
The crystal structure and magnetic properties of Co(HPO3)⋅H2O have been determined. The solid crysta...
The crystal structure and magnetic properties of Co(HPO3)⋅H2O have been determined. The solid crysta...
International audienceThe magnetic properties of a novel cobalt-based hydrogen vanadate, Co-13.5(OH)...
Previously unknown Co2(TeO3)(OH)2 and Co15(TeO3)14(OH)2 were obtained under mild hydrothermal reacti...
New tellurite–sulfate compounds M<sub>2</sub>(TeO<sub>3</sub>)(SO<sub>4</sub>)·H<sub>2</sub>O (M = ...
International audienceThe new oxofluoride Co15F2(TeO3)14 has been prepared by optimized hydrothermal...
International audienceThe structures (nuclear and magnetic), magnetic properties (2-300 K, 1-104 bar...
International audienceThe new oxofluoride Co15F2(TeO3)14 has been prepared by optimized hydrothermal...
International audienceNew Ni3TeO6-type (NTO) and double perovskite (DPv) polymorphs of Co3TeO6 are s...
In this study, we measured the temperature-dependent magnetic susceptibility [chi(T)], ac magnetic s...
International audienceNew Ni3TeO6-type (NTO) and double perovskite (DPv) polymorphs of Co3TeO6 are s...
International audienceNew Ni3TeO6-type (NTO) and double perovskite (DPv) polymorphs of Co3TeO6 are s...
A new framework cobalt(II) hydroxyl phosphate, Co2PO4OH, was prepared by ionothermal synthesis using...
The synthesis, characterization, crystal structure, and magnetic properties of Co2(OH)2BDC and Co(H2...
A new framework cobalt(II) hydroxyl phosphate, Co2PO4OH, was prepared by ionothermal synthesis using...
The crystal structure and magnetic properties of Co(HPO3)⋅H2O have been determined. The solid crysta...
The crystal structure and magnetic properties of Co(HPO3)⋅H2O have been determined. The solid crysta...
International audienceThe magnetic properties of a novel cobalt-based hydrogen vanadate, Co-13.5(OH)...