Laboratory intercomparison study for the analysis of nonylphenol and octylphenol in river water

International audienceIn support of the implementation of the European Union (EU) Water Framework Directive (WFD), the European Commission (EC)Joint Research Centre (JRC) organized a laboratory and sampling intercomparison study for the chemical monitoring of polyaromatichydrocarbons (PAHs), polybrominated diphenyl ethers (PBDEs), and nonylphenol and octylphenol (NP/OP), prioritysubstances of the WFD, in river water. EU Member State laboratories were invited to analyze a standard solution with unknownconcentration levels and a river-water extract, as well as a real water sample from the River Po (Italy). For the standard solutionand the river-water extract, good agreement was achieved for five laboratories. Triple-quadrupole liquid chromatography withtandem mass spectrometry (LC-MS) and gas chromatography with MS (GC-MS) with or without derivatization proved to becomparable methods for the analysis of NP and OP. Fluorescence detection can also be used to analyze NP and OP, but it is lessspecific. The results of the River Po water sample showed that some laboratories have problems in analyzing NP at concentrationlevels below 100 ng/L due to contamination of laboratory blanks. Plastics materials should not be used during extraction andsample preparation