Di-μ-Iodo-Bis[Diiodo(1,10-Phenanthroline)Bismuth(III)]
- Tershany, Meredith A.
- Goforth, Andrea M.
- Smith, Mark D.
- Peterson, LeRoy, Jr.
- zur Loye, Hans-Conrad
Publication date
October 2006
DOI Publisher
International Union of Crystallography (IUCr)Abstract
The title bismuth-iodide compound, [Bi2I6(C12H8N2)2], has been synthesized solvothermally by reacting BiI3, Mn(CH3COO)2·4H2O, and 1,10-phenanthroline in an ethanol/water solvent mixture. The compound contains two bismuth centers that are each coordinated by a phenanthroline ligand and two terminal iodide ligands, and the bismuth centers are bridged via two additional iodide ligands to form a molecular dimer. The asymmetric unit of the compound consists of one half of a single dimer molecule located on a crystallographic inversion center
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