Preventing thermolysis: Precursor design for volatile copper compounds
- Coyle, J.P. (Jason P.)
- Kurek, A. (Agnieszka)
- Pallister, P.J. (Peter J.)
- Sirianni, E.R. (Eric R.)
- Yap, G.P.A. (Glenn P. A.)
- Barry, S.T. (Seán T.)
Publication date
October 2012
DOI Publisher
Royal Society of Chemistry (RSC) ISSN
1359-7345 Citation count (estimate)
15Abstract
A copper(i) iminopyrrolidinate was synthesized and evaluated by thermal gravimetric analysis (TGA), solution based 1H NMR studies and surface chemistry to determine its thermal stability and decomposition mechanism. Copper(i) tert-butyl-imino-2,2-dimethylpyrrolidinate (1) demonstrated superior thermal stability and showed negligible decomposition in TGA experiments up to 300 °C as well as no decomposition in solutions at 165 °C over 3 weeks
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