Kowalski & Saumon identified the missing absorption mechanism in the observed spectra of cool white dwarf stars as the Lyman α red wing formed by the collisions between atomic and molecular hydrogen and successfully explained entire spectra of many cool DA-type white dwarfs. Owing to the important astrophysical implications of this issue, we present here an independent assessment of the process. For this purpose, we compute free–free quasi-molecular absorption in Lyman α due to collisions with H and H2 within the one-perturber, quasi-static approximation. Line cross-sections are obtained using theoretical molecular potentials to describe the interaction between the radiating atom and the perturber. The variation in the electric dipole trans...