Values of the rate constant for the reaction O(/sup 3/P) + NH/sub 3/ were determined by comparing calculated O atom profiles with those obtained experimentally in the temperature range 2069--2459K. Oxygen atoms were generated by thermal decomposition of N/sub 2/O. The results were combined with those from previous direct studies (448--1790K) to give the following expression 448--2459K: k/sub 2/(T) = 2.27 /times/ 10/sup /minus/18/ T/sup 2.19/ exp(/minus/3061/T) cm/sup 3/ molecule/sup /minus/1/ s/sup /minus/1/. An overall uncertainty of /plus minus/25% is estimated for this expression. 16 refs., 3 figs., 3 tabs
Semiclassical transition state theory, in combination with high accuracy quantum chemistry, is used ...
The rate of the reaction of N2O with O(3P) was investigated experimentally and by kinetic modelling ...
The absolute rate constant for the reaction that is the major source of stratospheric NOx, O(1D)+N2O...
Rate coefficients of the reaction O(3P) + C2H5OH in the temperature range 782-1410 K were determined...
This is the publisher's version, also available electronically from http://scitation.aip.org/content...
This is the publisher's version, also available electronically from http://scitation.aip.org/content...
The dissociation rate of O2 was measured at very high temperature (3000 K to 4500 K) for pressure be...
The dissociation rate of O2 was measured at very high temperature (3000 K to 4500 K) for pressure be...
International audienceWe have determined, in the temperature range 227 K to 719 K, the absolute rate...
The high-temperature photochemistry (HTP) and laser photolysis-shock tube (LP-ST) techniques have be...
The shock tube technique was used to study the thermal decomposition of ozone, O<sub>3</sub>, with a...
Rate coefficients (<i>k</i><sub>5</sub>) for the title reaction were obtained using pulsed laser pho...
The reaction between H{sub 2}CO and O{sub 2} has been studied in a reflected shock tube apparatus be...
International audienceA discharge-flow modulated molecular beam mass spectrometry technique has been...
The gas phase reaction O + O3 yields 2 O2 was studied directly in a flow system under conditions of ...
Semiclassical transition state theory, in combination with high accuracy quantum chemistry, is used ...
The rate of the reaction of N2O with O(3P) was investigated experimentally and by kinetic modelling ...
The absolute rate constant for the reaction that is the major source of stratospheric NOx, O(1D)+N2O...
Rate coefficients of the reaction O(3P) + C2H5OH in the temperature range 782-1410 K were determined...
This is the publisher's version, also available electronically from http://scitation.aip.org/content...
This is the publisher's version, also available electronically from http://scitation.aip.org/content...
The dissociation rate of O2 was measured at very high temperature (3000 K to 4500 K) for pressure be...
The dissociation rate of O2 was measured at very high temperature (3000 K to 4500 K) for pressure be...
International audienceWe have determined, in the temperature range 227 K to 719 K, the absolute rate...
The high-temperature photochemistry (HTP) and laser photolysis-shock tube (LP-ST) techniques have be...
The shock tube technique was used to study the thermal decomposition of ozone, O<sub>3</sub>, with a...
Rate coefficients (<i>k</i><sub>5</sub>) for the title reaction were obtained using pulsed laser pho...
The reaction between H{sub 2}CO and O{sub 2} has been studied in a reflected shock tube apparatus be...
International audienceA discharge-flow modulated molecular beam mass spectrometry technique has been...
The gas phase reaction O + O3 yields 2 O2 was studied directly in a flow system under conditions of ...
Semiclassical transition state theory, in combination with high accuracy quantum chemistry, is used ...
The rate of the reaction of N2O with O(3P) was investigated experimentally and by kinetic modelling ...
The absolute rate constant for the reaction that is the major source of stratospheric NOx, O(1D)+N2O...