L-shell photoabsorption spectroscopy for solid metals: Ti, V, Cr, Fe, Ni, Cu

Synchrotron radiation measurements of near-threshold and broad-range (400--1500 eV) absolute photoabsorption cross sections were made for five transition metals with {plus minus}10% overall uncertainties. Fine structure details of 2p-3d autoionizing resonances are shown with better than 1.0 eV resolution for solid metals: Ti, V, Cr, Fe, Ni, and Cu. Fine structure similar to what we measured can be produced using a multi-configuration Dirac Fock (MCDF) model if a statistical distribution is assumed for the initial atomic states. Calculations were performed in intermediate coupling with configuration interactions by Mau H. Chen. The results are compared with other experimental work and theoretical methodologies. 18 refs., 7 figs