Growth, preparation, and dielectric properties of monodomain single crystal PbTiO sub 3

A method is described for obtaining monodomain PbTiO{sub 3} single crystals with high electrical resistivity (10{sup 10}{Omega} cm) and low dielectric frequency dispersion. The single crystals of PbTiO{sub 3} were grown by flux solution method. Space charge related defects, which result in the large dielectric frequency dispersion, were eliminated by heat treatments. 90{degrees} domains were removed by applying a unidirectional compressive stress along the <100> crystallographic direction. The monodomain single crystals of PbTiO{sub 3} were identified by cross polarized light optical microscopy and by X-ray diffraction (rocking curve). The anisotropic dielectric constants of these high quality single crystals were measured as a function of temperature. The results differ from the data reported previously in the literature