Add to ORKGWe have used femtosecond resolution UV-visible and Kβ x-ray emission spectroscopy to characterize the electronic excited state dynamics of [Fe(bpy)_2(CN)_2], where bpy=2,2'-bipyridine, initiated by metal-to-ligand charge transfer (MLCT) excitation. The excited-state absorption in the transient UV-visible spectra, associated with the 2,2'-bipyridine radical anion, provides a robust marker for the MLCT excited state, while the transient Kβ x-ray emission spectra provide a clear measure of intermediate and high spin metal-centered excited states. From these measurements, we conclude that the MLCT state of [Fe(bpy)_2(CN)_2] undergoes ultrafast spin crossover to a metal-centered quintet excited state through a short lived metal-centered triplet ...
Photoinduced spin flip in FeII complexes is an ultrafast phenomenon that has the potential to become...
The photoinduced energy and structural relaxation of aq. iron(II)-tris-bipyridine ([FeII(bpy)3]2+), ...
The photoinduced energy and structural relaxation of aqueous iron(II)-tris-bipyridine ([FeII(bpy)3]2...
We have used femtosecond resolution UV-visible and Kβ x-ray emission spectroscopy to characterize th...
We have used femtosecond resolution UV-visible and Kβ x-ray emission spectroscopy to characterize th...
We have used femtosecond resolution UV-visible and Kβ x-ray emission spectroscopy to characterize th...
We have used femtosecond resolution UV-visible and Kβ x-ray emission spectroscopy to characterize th...
Developing light-harvesting and photocatalytic molecules made with iron could provide a cost effecti...
Developing light-harvesting and photocatalytic molecules made with iron could provide a cost effecti...
Crucial to many light-driven processes in transition metal complexes is the absorption and dissipati...
The mechanism of the light-induced spin crossover of the [Fe(bpy)(3)](2+) complex (bpy=2,2-bipyridin...
Crucial to many light-driven processes in transition metal complexes is the absorption and dissipati...
The excited state dynamics of solvated [Fe(bpy)(CN)4]2-, where bpy = 2,2′-bipyridine, show significa...
The excited state dynamics of solvated $[Fe(bpy)(CN)_{4}]^{2−}$, where bpy = 2,2′-bipyridine, show s...
It is known that excitation by visible light of the singlet metal-to-ligand charge-transfer (1MLCT) ...
Photoinduced spin flip in FeII complexes is an ultrafast phenomenon that has the potential to become...
The photoinduced energy and structural relaxation of aq. iron(II)-tris-bipyridine ([FeII(bpy)3]2+), ...
The photoinduced energy and structural relaxation of aqueous iron(II)-tris-bipyridine ([FeII(bpy)3]2...
We have used femtosecond resolution UV-visible and Kβ x-ray emission spectroscopy to characterize th...
We have used femtosecond resolution UV-visible and Kβ x-ray emission spectroscopy to characterize th...
We have used femtosecond resolution UV-visible and Kβ x-ray emission spectroscopy to characterize th...
We have used femtosecond resolution UV-visible and Kβ x-ray emission spectroscopy to characterize th...
Developing light-harvesting and photocatalytic molecules made with iron could provide a cost effecti...
Developing light-harvesting and photocatalytic molecules made with iron could provide a cost effecti...
Crucial to many light-driven processes in transition metal complexes is the absorption and dissipati...
The mechanism of the light-induced spin crossover of the [Fe(bpy)(3)](2+) complex (bpy=2,2-bipyridin...
Crucial to many light-driven processes in transition metal complexes is the absorption and dissipati...
The excited state dynamics of solvated [Fe(bpy)(CN)4]2-, where bpy = 2,2′-bipyridine, show significa...
The excited state dynamics of solvated $[Fe(bpy)(CN)_{4}]^{2−}$, where bpy = 2,2′-bipyridine, show s...
It is known that excitation by visible light of the singlet metal-to-ligand charge-transfer (1MLCT) ...
Photoinduced spin flip in FeII complexes is an ultrafast phenomenon that has the potential to become...
The photoinduced energy and structural relaxation of aq. iron(II)-tris-bipyridine ([FeII(bpy)3]2+), ...
The photoinduced energy and structural relaxation of aqueous iron(II)-tris-bipyridine ([FeII(bpy)3]2...