A thermally and air stable O-donor, iridium−methoxo complex is reported that undergoes stoichiometric, intermolecular C−H activation of benzene with co-generation of methanol and the iridium−phenyl complex
A bis(phenolate)pyridine pincer ligand (henceforth abbreviated as ONO) has been employed to support ...
Four complexes of the type [Rh(CO)Cl(�2-P,O-L)](1a,1b) and [Rh(CO)Cl(�1-P-L)2](2a,2b), where L = Ph...
The mechanism responsible for C−H activation in Ir(acac)_2(OCH_3)(C_6H_6) has been identified and de...
A thermally and air stable O-donor, iridium−methoxo complex is reported that undergoes stoichiometri...
A well-defined, O-donor ligated iridium hydroxide complex is reported that is competent for benzene ...
UnrestrictedThis dissertation describes a veritable smorgasbord of organometallic chemistry, includi...
A discrete, air, protic, and thermally stable (NNC)Ir(III) pincer complex was synthesized that catal...
The mechanism of benzene C−H bond activation by [Ir(μ-acac-O,O,C^3)(acac-O,O)(OAc)]_2 (4) and [Ir(μ-...
Olefin dimerizations are typically proposed to proceed via a Cossee−Arlman type migratory mechanism ...
We report on the design of more efficient C−H activation catalysts based on DFT calculations. The fi...
We report on the design of more efficient C−H activation catalysts based on DFT calculations. The fi...
Using tetradentate, dianionic ligands, several new rhodium complexes have been prepared. Some of the...
Olefin dimerizations are typically proposed to proceed via a Cossee−Arlman type migratory mechanism ...
A square-planar, iridium(I) carbene complex is shown to effect atom and group transfer from nitrous ...
A reaction cascade comprising a rhodium-catalyzed C−H activation, a subsequent hydrometalation of an...
A bis(phenolate)pyridine pincer ligand (henceforth abbreviated as ONO) has been employed to support ...
Four complexes of the type [Rh(CO)Cl(�2-P,O-L)](1a,1b) and [Rh(CO)Cl(�1-P-L)2](2a,2b), where L = Ph...
The mechanism responsible for C−H activation in Ir(acac)_2(OCH_3)(C_6H_6) has been identified and de...
A thermally and air stable O-donor, iridium−methoxo complex is reported that undergoes stoichiometri...
A well-defined, O-donor ligated iridium hydroxide complex is reported that is competent for benzene ...
UnrestrictedThis dissertation describes a veritable smorgasbord of organometallic chemistry, includi...
A discrete, air, protic, and thermally stable (NNC)Ir(III) pincer complex was synthesized that catal...
The mechanism of benzene C−H bond activation by [Ir(μ-acac-O,O,C^3)(acac-O,O)(OAc)]_2 (4) and [Ir(μ-...
Olefin dimerizations are typically proposed to proceed via a Cossee−Arlman type migratory mechanism ...
We report on the design of more efficient C−H activation catalysts based on DFT calculations. The fi...
We report on the design of more efficient C−H activation catalysts based on DFT calculations. The fi...
Using tetradentate, dianionic ligands, several new rhodium complexes have been prepared. Some of the...
Olefin dimerizations are typically proposed to proceed via a Cossee−Arlman type migratory mechanism ...
A square-planar, iridium(I) carbene complex is shown to effect atom and group transfer from nitrous ...
A reaction cascade comprising a rhodium-catalyzed C−H activation, a subsequent hydrometalation of an...
A bis(phenolate)pyridine pincer ligand (henceforth abbreviated as ONO) has been employed to support ...
Four complexes of the type [Rh(CO)Cl(�2-P,O-L)](1a,1b) and [Rh(CO)Cl(�1-P-L)2](2a,2b), where L = Ph...
The mechanism responsible for C−H activation in Ir(acac)_2(OCH_3)(C_6H_6) has been identified and de...