Add to ORKGThe title compound, dichlorobis(methyldiphenylphosphine-P) [(1,2-[η])-3,3-diphenylcyclopropene]oxotungsten, [WCl_2O(C_(15)H_(12))(C_(13)H_(13)P)_2], is a mononuclear complex of tungsten with an approximately octahedral environment around the metal atom. The ligand, 3,3-diphenylcyclopropene, is bonded to the W atom in a [η]^2-geometry with effectively identical metal-to-carbon bond distances [W-C1 = 2.133 (7) Å and W-C2 2.131 (7) Å]
Reaction of W(O)<sub>2</sub>(CH<sub>2</sub>-<i>t</i>-Bu)<sub>2</sub>(bipy) with a mixture of ZnCl<s...
The metathesis reaction of Cp*(CO)3MoBr and NaW(CO)3Cp produced Cp*(CO)3Mo–W(CO)3Cp (1), featuring a...
This paper reports the alkylation of the cyclopentadienyl imido tungsten complexes [WCp′(NtBu)Cl3] (...
A binuclear tungsten(0) complex with an asymmetric bridging 1,2-diphosphole ligand was prepared by t...
Complexes of the type WCl_2(O)[PX_3]_3 (PX_3 = P(OMe)_3 (1); PMePh_2 (2)) were synthesized according...
The η⁵-C₅H₄iPr ligand imparts unprecedented effects on the physical and chemical properties of (η⁵-C...
Previous work with tungsten(II) acetylacetonate complexes has focused on synthesis of complexes with...
Bibliography: pages 133-139.The extensive series of cyclopentadienyl transition metal complexes know...
The reactions of the ditungstaoctatetrayne [(Tp*)(CO)2W([triple bond, length as m-dash]CC[triple bon...
One continuing problem with the development of the early transition metal chemistry of sterically de...
© CSIRO 2001Reactions between W(C≡CC≡CH)(CO)3Cp (1) and {Mo(CO)2Cp}2, Pt(η-C2H4)(PPh3)2 and 1,4-I2C6...
Reduction of tungsten(IV) chloride with metals was studied in order to find a high-yield and conveni...
Alternative methods to prepare [MCp'C14], [MCp'CL(N'Bu)] and [MCp'CI~(N'Bu)] [M=Mo, Cp'="qs-C~Me~ (C...
Thesis: Ph. D., Massachusetts Institute of Technology, Department of Chemistry, 2015.Cataloged from ...
ABSTRACT: We report the synthesis of Mo and W MAP complexes that contain O-2,6-(2,5-R2-pyrrolyl)2C6H...
Reaction of W(O)<sub>2</sub>(CH<sub>2</sub>-<i>t</i>-Bu)<sub>2</sub>(bipy) with a mixture of ZnCl<s...
The metathesis reaction of Cp*(CO)3MoBr and NaW(CO)3Cp produced Cp*(CO)3Mo–W(CO)3Cp (1), featuring a...
This paper reports the alkylation of the cyclopentadienyl imido tungsten complexes [WCp′(NtBu)Cl3] (...
A binuclear tungsten(0) complex with an asymmetric bridging 1,2-diphosphole ligand was prepared by t...
Complexes of the type WCl_2(O)[PX_3]_3 (PX_3 = P(OMe)_3 (1); PMePh_2 (2)) were synthesized according...
The η⁵-C₅H₄iPr ligand imparts unprecedented effects on the physical and chemical properties of (η⁵-C...
Previous work with tungsten(II) acetylacetonate complexes has focused on synthesis of complexes with...
Bibliography: pages 133-139.The extensive series of cyclopentadienyl transition metal complexes know...
The reactions of the ditungstaoctatetrayne [(Tp*)(CO)2W([triple bond, length as m-dash]CC[triple bon...
One continuing problem with the development of the early transition metal chemistry of sterically de...
© CSIRO 2001Reactions between W(C≡CC≡CH)(CO)3Cp (1) and {Mo(CO)2Cp}2, Pt(η-C2H4)(PPh3)2 and 1,4-I2C6...
Reduction of tungsten(IV) chloride with metals was studied in order to find a high-yield and conveni...
Alternative methods to prepare [MCp'C14], [MCp'CL(N'Bu)] and [MCp'CI~(N'Bu)] [M=Mo, Cp'="qs-C~Me~ (C...
Thesis: Ph. D., Massachusetts Institute of Technology, Department of Chemistry, 2015.Cataloged from ...
ABSTRACT: We report the synthesis of Mo and W MAP complexes that contain O-2,6-(2,5-R2-pyrrolyl)2C6H...
Reaction of W(O)<sub>2</sub>(CH<sub>2</sub>-<i>t</i>-Bu)<sub>2</sub>(bipy) with a mixture of ZnCl<s...
The metathesis reaction of Cp*(CO)3MoBr and NaW(CO)3Cp produced Cp*(CO)3Mo–W(CO)3Cp (1), featuring a...
This paper reports the alkylation of the cyclopentadienyl imido tungsten complexes [WCp′(NtBu)Cl3] (...