Add to ORKGThe dynamics of I_2 dissociation and recombination (caging) in a macrocluster are reported, covering the femtosecond to picosecond time domain. Both the exit-channel and recombination dynamics are observed and related to solute—solvent interactions. The dissociation involves bond breakage on bound/repulsive potentials with concomitant evaporation of the solvent shell. The caging is accompanied by relaxation of the system and/or diffusion of the free iodine atoms prior to reforming the I_2 bond. Molecular dynamics are used to compare with experiments
Ultrafast dissociation and recombination dynamics of (O_2)^−_n, n=3–10 was studied using femtosecond...
The femtosecond reaction dynamics of ICN in the liquids CHCl_3, CH_2Cl_2, and CDCl_3 are reported. A...
Pump-probe studies of I2 in matrix Ar, with a time resolution of 180 fs, are reported. The experimen...
The dynamics of I_2 dissociation and recombination (caging) in a macrocluster are reported, covering...
For chemical reactions in solution, the solvent exerts an important influence on the elementary proc...
In this paper we give a full account of the work presented in earlier communications [Lienau et al. ...
The method of femtosecond velocity-gating in complex systems is reported with an application to the ...
The femtosecond solvation dynamics of an elementary chemical reaction in the gas-to-liquid transitio...
The many-body dynamics resulting from I2 photodissociation in solid Ar are investigated using a comb...
In this paper, our focus is on the influence of the solvent density on the caging, recombination dyn...
Previous experiments have been carried out in this laboratory to investigate the dynamics of iodine−...
We report studies of the femtosecond dynamics of reactions in confined nanocavities in water solutio...
The summary presented here attempts to describe recent studies in our laboratory of the effect of mi...
Author Institution: JILA and Department of Chemistry, University of Colorado, Boulder, CO 80309Ultra...
In this paper of the series, which gives the full account of an earlier communication [Liu et al. J....
Ultrafast dissociation and recombination dynamics of (O_2)^−_n, n=3–10 was studied using femtosecond...
The femtosecond reaction dynamics of ICN in the liquids CHCl_3, CH_2Cl_2, and CDCl_3 are reported. A...
Pump-probe studies of I2 in matrix Ar, with a time resolution of 180 fs, are reported. The experimen...
The dynamics of I_2 dissociation and recombination (caging) in a macrocluster are reported, covering...
For chemical reactions in solution, the solvent exerts an important influence on the elementary proc...
In this paper we give a full account of the work presented in earlier communications [Lienau et al. ...
The method of femtosecond velocity-gating in complex systems is reported with an application to the ...
The femtosecond solvation dynamics of an elementary chemical reaction in the gas-to-liquid transitio...
The many-body dynamics resulting from I2 photodissociation in solid Ar are investigated using a comb...
In this paper, our focus is on the influence of the solvent density on the caging, recombination dyn...
Previous experiments have been carried out in this laboratory to investigate the dynamics of iodine−...
We report studies of the femtosecond dynamics of reactions in confined nanocavities in water solutio...
The summary presented here attempts to describe recent studies in our laboratory of the effect of mi...
Author Institution: JILA and Department of Chemistry, University of Colorado, Boulder, CO 80309Ultra...
In this paper of the series, which gives the full account of an earlier communication [Liu et al. J....
Ultrafast dissociation and recombination dynamics of (O_2)^−_n, n=3–10 was studied using femtosecond...
The femtosecond reaction dynamics of ICN in the liquids CHCl_3, CH_2Cl_2, and CDCl_3 are reported. A...
Pump-probe studies of I2 in matrix Ar, with a time resolution of 180 fs, are reported. The experimen...