Add to ORKGThe first enantioselective total synthesis of the cytotoxic natural product (+)-psiguadial B is reported. Key features of the synthesis include (1) the enantioselective preparation of a key cyclobutane intermediate by a tandem Wolff rearrangement/asymmetric ketene addition, (2) a directed C(sp^3)–H alkenylation reaction to strategically forge the C1–C2 bond, and (3) a ring-closing metathesis to build the bridging bicyclo[4.3.1]decane terpene framework
Stereoconvergent cyclocondensation reactions of (R)- or (S)-phenylglycinol with appropriately substi...
An enantioselective total synthesis of the diterpenoid natural product (+)-salvileucalin B is repo...
Herein we report the first enantioselective total synthesis of (+)-dichroanone, confirming the absol...
The first enantioselective total synthesis of the cytotoxic natural product (+)-psiguadial B is repo...
Trans-cyclobutane-containing meroterpenoids are a structurally intriguing class of natural products ...
(+)-Psiguadial B is a diformyl phloroglucinol meroterpenoid that exhibits antiproliferative activity...
The de novo synthesis of bioactive natural products provides an opportunity to learn more about the ...
Progress toward the total synthesis of psiguadial B, a diformyl phloroglucinol meroterpenoid natural...
Progress toward the total synthesis of psiguadial B, a diformyl phloroglucinol meroterpenoid natural...
(+)-Psiguadial B is a diformyl phloroglucinol meroterpenoid that exhibits antiproliferative activit...
A concise and versatile approach toward the preparation of the cyanthiwigin family of cyathane natur...
A modular synthesis of enantioenriched polyfunctionalized cyclobutanes was developed that features a...
No strain, no gain! The first transition metal-catalyzed enantioselective α-alkylation of cyclobutan...
No strain, no gain! The first transition metal-catalyzed enantioselective α-alkylation of cyclobutan...
A tandem anionic 5-exo-dig cyclization/Claisen rearrangement sequence was used to effect a facile, “...
Stereoconvergent cyclocondensation reactions of (R)- or (S)-phenylglycinol with appropriately substi...
An enantioselective total synthesis of the diterpenoid natural product (+)-salvileucalin B is repo...
Herein we report the first enantioselective total synthesis of (+)-dichroanone, confirming the absol...
The first enantioselective total synthesis of the cytotoxic natural product (+)-psiguadial B is repo...
Trans-cyclobutane-containing meroterpenoids are a structurally intriguing class of natural products ...
(+)-Psiguadial B is a diformyl phloroglucinol meroterpenoid that exhibits antiproliferative activity...
The de novo synthesis of bioactive natural products provides an opportunity to learn more about the ...
Progress toward the total synthesis of psiguadial B, a diformyl phloroglucinol meroterpenoid natural...
Progress toward the total synthesis of psiguadial B, a diformyl phloroglucinol meroterpenoid natural...
(+)-Psiguadial B is a diformyl phloroglucinol meroterpenoid that exhibits antiproliferative activit...
A concise and versatile approach toward the preparation of the cyanthiwigin family of cyathane natur...
A modular synthesis of enantioenriched polyfunctionalized cyclobutanes was developed that features a...
No strain, no gain! The first transition metal-catalyzed enantioselective α-alkylation of cyclobutan...
No strain, no gain! The first transition metal-catalyzed enantioselective α-alkylation of cyclobutan...
A tandem anionic 5-exo-dig cyclization/Claisen rearrangement sequence was used to effect a facile, “...
Stereoconvergent cyclocondensation reactions of (R)- or (S)-phenylglycinol with appropriately substi...
An enantioselective total synthesis of the diterpenoid natural product (+)-salvileucalin B is repo...
Herein we report the first enantioselective total synthesis of (+)-dichroanone, confirming the absol...