Add to ORKGInterconversion of chair conformations of six-membered rings containing two identical heteroatoms has been much studied by the nmr method, with the exception of the 1,4-dithiane system. The results so far obtained for 1,2- and 1,3-dithianes in comparison with those of dioxanes and the corresponding diaza systems suggest that this barrier should be readily measureable by the nmr method. We are concerned here with the ring inversion of octafluoro-1,4-dithiane (1)
A number of 1,3-dithianes substituted with trimethylsilyl, stannyl, and plumbyl groups at the 2-posi...
In a series of N-alkoxy- and N-alkyl-2,2,6,6-tetramethylpiperidines, the temperature dependence of N...
The chemistry of a range of N-methyl-1,4-dihydro- and 1,2,3,4-tetrahydronaphthalen-1,4-imines has be...
[[abstract]]Four 1,1,2,2-tetrafluoro-l,2-disilacyclohexadneer ivatives are synthesized. The conforma...
In a recent communication, the barrier to chair-chair interconversion in 1,1 -dimethyl-4,4-dibenzylc...
A theoretical study on the conformational interconversions in 1,3-dithiane 1,1-dioxide (1,3-dithiane...
Rates of ring inversion of 1,1-difluorocyclodecane were obtained from line-shape changes in the low-...
The rate of ring inversion of fluorocyclohexane in the solid inclusion compound that it forms with t...
Two-dimensional NMR spectroscopy was used to establish that the chair ⇄ chair-inversion process in 2...
Rates of ring inversion and conformational equilibria of gem-fluorocyclohexanes carrying various sub...
Interconversion reaction of I ⇔ II conformers of 4-ethyl-6-methyl-1,3-dithiane (METDIT) has been stu...
Variable-temperature F-19 magic-angle spinning NMR experiments involving high-power proton decouplin...
Using the high dilution methods, 1,3,4,6-tetrahydrobenzo[f][1,4]dithiocine and 2,3,4,5-tetrahydroben...
The stereochemical peculiarities of substituted 1,3-dioxanes and 1,3-dithianes are discussed. The hi...
The preferential conformations of a series of six–membered saturated heterocycles containing oxygen ...
A number of 1,3-dithianes substituted with trimethylsilyl, stannyl, and plumbyl groups at the 2-posi...
In a series of N-alkoxy- and N-alkyl-2,2,6,6-tetramethylpiperidines, the temperature dependence of N...
The chemistry of a range of N-methyl-1,4-dihydro- and 1,2,3,4-tetrahydronaphthalen-1,4-imines has be...
[[abstract]]Four 1,1,2,2-tetrafluoro-l,2-disilacyclohexadneer ivatives are synthesized. The conforma...
In a recent communication, the barrier to chair-chair interconversion in 1,1 -dimethyl-4,4-dibenzylc...
A theoretical study on the conformational interconversions in 1,3-dithiane 1,1-dioxide (1,3-dithiane...
Rates of ring inversion of 1,1-difluorocyclodecane were obtained from line-shape changes in the low-...
The rate of ring inversion of fluorocyclohexane in the solid inclusion compound that it forms with t...
Two-dimensional NMR spectroscopy was used to establish that the chair ⇄ chair-inversion process in 2...
Rates of ring inversion and conformational equilibria of gem-fluorocyclohexanes carrying various sub...
Interconversion reaction of I ⇔ II conformers of 4-ethyl-6-methyl-1,3-dithiane (METDIT) has been stu...
Variable-temperature F-19 magic-angle spinning NMR experiments involving high-power proton decouplin...
Using the high dilution methods, 1,3,4,6-tetrahydrobenzo[f][1,4]dithiocine and 2,3,4,5-tetrahydroben...
The stereochemical peculiarities of substituted 1,3-dioxanes and 1,3-dithianes are discussed. The hi...
The preferential conformations of a series of six–membered saturated heterocycles containing oxygen ...
A number of 1,3-dithianes substituted with trimethylsilyl, stannyl, and plumbyl groups at the 2-posi...
In a series of N-alkoxy- and N-alkyl-2,2,6,6-tetramethylpiperidines, the temperature dependence of N...
The chemistry of a range of N-methyl-1,4-dihydro- and 1,2,3,4-tetrahydronaphthalen-1,4-imines has be...