Add to ORKGThe rate of inversion of 7,7-dicyano-2,5-bis(difluoromethyl)norcaradiene (10), presumably by way of its valence tautomer, 7,7-dicyano-2,5-bis(difluoromethyl)cycloheptatrien (11), was studied through the temperature dependence of the magnetic nonequivalence of the gem-fluoro groups. The activation energy E, was found to be 14.6 ± 0.4 kcal/mol and log A is 13.4 ± 0.3
Rates of ring inversion and conformational equilibria of gem-fluorocyclohexanes carrying various sub...
The kinetics of the degenerate isomerization about the carbon-nitrogen double bond of hexafluoroacet...
The fluorine-19 magnetic resonance spectra of 2,2-difluoro-cis-decalin and some of its derivatives h...
The rate of inversion of 7,7-dicyano-2,5-bis(difluoromethyl)norcaradiene (10), presumably by way of ...
The equilibria of 7-phenyl-, 7-(p-nitrophenyl)-, and 7-(p-methoxyphenyl)-7-carbomethoxynorcaradiene ...
Complete analyses of the room-temperature proton spectra of cycloheptatriene (I) and its 7,7-bistrif...
Fluorine magnetic resonance spectroscopy has been used to measure the rates of inversion of 4,4-difl...
The rates of ring inversion and conformational equilibration of 6,6-difluoro-cis-decal-2-one and 10-...
The rate of ring inversion and conformational equilibration of 5,5-difluoro-cis-hydrindahn as been d...
The fluorine n.m.r. spectrum of fluorocyclootatetraene has been shown to be temperature dependent be...
Rates of ring inversion of 1,1-difluorocyclodecane were obtained from line-shape changes in the low-...
The rate of ring inversion in 3,5,7-cyclooctatrienone was determined by the temperature dependence o...
Fluorine magnetic resonance spectroscopy has been used to determine the rates of ring inversion of y...
PART 1: Conformational inversion in the 9, 10-o-xylylene-anthracene system was investigated by vari...
Kinetic parameters for ring inversion of perfluorocyclohexene and 1,2-dichlorooctafluorocyclohexene ...
Rates of ring inversion and conformational equilibria of gem-fluorocyclohexanes carrying various sub...
The kinetics of the degenerate isomerization about the carbon-nitrogen double bond of hexafluoroacet...
The fluorine-19 magnetic resonance spectra of 2,2-difluoro-cis-decalin and some of its derivatives h...
The rate of inversion of 7,7-dicyano-2,5-bis(difluoromethyl)norcaradiene (10), presumably by way of ...
The equilibria of 7-phenyl-, 7-(p-nitrophenyl)-, and 7-(p-methoxyphenyl)-7-carbomethoxynorcaradiene ...
Complete analyses of the room-temperature proton spectra of cycloheptatriene (I) and its 7,7-bistrif...
Fluorine magnetic resonance spectroscopy has been used to measure the rates of inversion of 4,4-difl...
The rates of ring inversion and conformational equilibration of 6,6-difluoro-cis-decal-2-one and 10-...
The rate of ring inversion and conformational equilibration of 5,5-difluoro-cis-hydrindahn as been d...
The fluorine n.m.r. spectrum of fluorocyclootatetraene has been shown to be temperature dependent be...
Rates of ring inversion of 1,1-difluorocyclodecane were obtained from line-shape changes in the low-...
The rate of ring inversion in 3,5,7-cyclooctatrienone was determined by the temperature dependence o...
Fluorine magnetic resonance spectroscopy has been used to determine the rates of ring inversion of y...
PART 1: Conformational inversion in the 9, 10-o-xylylene-anthracene system was investigated by vari...
Kinetic parameters for ring inversion of perfluorocyclohexene and 1,2-dichlorooctafluorocyclohexene ...
Rates of ring inversion and conformational equilibria of gem-fluorocyclohexanes carrying various sub...
The kinetics of the degenerate isomerization about the carbon-nitrogen double bond of hexafluoroacet...
The fluorine-19 magnetic resonance spectra of 2,2-difluoro-cis-decalin and some of its derivatives h...