Add to ORKGThe CAAC [CAAC=cyclic (alkyl)(amino)carbene] family of carbene ligands have shown promise in stabilizing unusually low-coordination number transition-metal complexes in low formal oxidation states. Here we extend this narrative by demonstrating their utility in affording access to the first examples of two-coordinate formal Fe^0 and Co^0 [(CAAC)_2M] complexes, prepared by reduction of their corresponding two-coordinate cationic Fe^I and Co^I precursors. The stability of these species arises from the strong σ-donating and π-accepting properties of the supporting CAAC ligands, in addition to steric protection
A variety of half-sandwich iron(II) complexes with diprotic acyclic diaminocarbene ligands (pADCs) h...
The use of the N-heterocyclic carbene (NHC) ligands 1,3-bis(2′,6′-diethylphenyl)-4,5-(CH<sub>2</sub...
Thesis (Ph. D.)--University of Rochester. Department of Chemistry, 2016.First-row transition metal c...
The CAAC [CAAC=cyclic (alkyl)(amino)carbene] family of carbene ligands have shown promise in stabili...
Low coordinate iron and cobalt complexes are sought after for their catalytic applications as well a...
Cyclic (alkyl) (amino)carbenes (CAACs) are highly nucleophilic and electrophilic species. By utilizi...
The bulky bis(carbene)borate ligand Ph<sub>2</sub>B(<sup>t</sup>BuIm)<sub>2</sub><sup>–</sup> sta...
Low co-ordinate transition metal complexes have attracted much interest in recent years due to their...
Despite their promising metal–ligand cooperative reactivity, PCcarbeneP pincer ligands are rarely r...
(Me<sub>2</sub>-cAAC<b>:</b>)<sub>2</sub>Co<sub>2</sub> (<b>2</b>, where Me<sub>2</sub>-cAAC<b>:</b>...
Cyclic alkyl(amino) carbene stabilized two- and three-coordinate Fe(I) complexes, (cAAC)<sub>2</su...
A new family of low-coordinate Co complexes supported by three redox-noninnocent tridentate [OCO] pi...
Addition of cyanide ions to the alkynyl(methoxy)carbene complexes [Fe2{μ-CN(Me)(R)}(μ-CO)...
Stable carbenes react with [Fe(cot)_2] in very different ways. Whereas the classical N-heterocyclic ...
A variety of half-sandwich iron(II) complexes with diprotic acyclic diaminocarbene ligands (pADCs) h...
The use of the N-heterocyclic carbene (NHC) ligands 1,3-bis(2′,6′-diethylphenyl)-4,5-(CH<sub>2</sub...
Thesis (Ph. D.)--University of Rochester. Department of Chemistry, 2016.First-row transition metal c...
The CAAC [CAAC=cyclic (alkyl)(amino)carbene] family of carbene ligands have shown promise in stabili...
Low coordinate iron and cobalt complexes are sought after for their catalytic applications as well a...
Cyclic (alkyl) (amino)carbenes (CAACs) are highly nucleophilic and electrophilic species. By utilizi...
The bulky bis(carbene)borate ligand Ph<sub>2</sub>B(<sup>t</sup>BuIm)<sub>2</sub><sup>–</sup> sta...
Low co-ordinate transition metal complexes have attracted much interest in recent years due to their...
Despite their promising metal–ligand cooperative reactivity, PCcarbeneP pincer ligands are rarely r...
(Me<sub>2</sub>-cAAC<b>:</b>)<sub>2</sub>Co<sub>2</sub> (<b>2</b>, where Me<sub>2</sub>-cAAC<b>:</b>...
Cyclic alkyl(amino) carbene stabilized two- and three-coordinate Fe(I) complexes, (cAAC)<sub>2</su...
A new family of low-coordinate Co complexes supported by three redox-noninnocent tridentate [OCO] pi...
Addition of cyanide ions to the alkynyl(methoxy)carbene complexes [Fe2{μ-CN(Me)(R)}(μ-CO)...
Stable carbenes react with [Fe(cot)_2] in very different ways. Whereas the classical N-heterocyclic ...
A variety of half-sandwich iron(II) complexes with diprotic acyclic diaminocarbene ligands (pADCs) h...
The use of the N-heterocyclic carbene (NHC) ligands 1,3-bis(2′,6′-diethylphenyl)-4,5-(CH<sub>2</sub...
Thesis (Ph. D.)--University of Rochester. Department of Chemistry, 2016.First-row transition metal c...