In situ measurements of hydrogen, nitrogen, and chlorine radicals obtained in the lower stratosphere during SPADE are compared to results from a photochemical model that assimilates measurements of radical precursors and environmental conditions. Models allowing for heterogeneous hydrolysis of N_2O_5 agree well with measured concentrations of NO and ClO, but concentrations of HO_2 and OH are underestimated by 10 to 25%, concentrations of NO_2 are overestimated by 10 to 30%, and concentrations of HCl are overestimated by a factor of 2. Discrepancies for [OH] and [HO_2] are reduced if we allow for higher yields of O(^1D) from O_3 photolysis and for heterogeneous production of HNO_2. The data suggest more efficient catalytic removal of O_3 by ...
ER-2 aircraft observations of OH and HO_2 concentrations in the upper troposphere during the NASA/ST...
ER-2 aircraft observations of OH and HO_2 concentrations in the upper troposphere during the NASA/ST...
A summary of the first order scientific conclusions that emerged from the research done under this g...
In situ measurements of hydrogen, nitrogen, and chlorine radicals obtained in the lower stratosphere...
In situ measurements of hydrogen, nitrogen, and chlorine radicals obtained through sunrise and sunse...
In situ measurements of hydrogen, nitrogen, and chlorine radicals obtained through sunrise and sunse...
Measurements of the ratio OH/HO_2, NO, O_3, ClO, and BrO were obtained at altitudes from 15–20 km an...
Measurements of the ratio OH/HO_2, NO, O_3, ClO, and BrO were obtained at altitudes from 15–20 km an...
Extensive airborne measurements of the reactive nitrogen reservoir (NO_(y)) and its component nitric...
Using observations from balloon-borne instruments and aircraft-borne instruments the investigation a...
The response of ClO concentrations to changes in NO_2 concentrations has been inferred from simultan...
The response of ClO concentrations to changes in NO_2 concentrations has been inferred from simultan...
Recent studies using NO, NO(y), OH and HO2 (HO(X)) observations have postulated acetone and convecti...
Extensive airborne measurements of the reactive nitrogen reservoir (NOy) and its component nitric ox...
The objective of this research was to gain a more thorough understanding of the atmospheric processe...
ER-2 aircraft observations of OH and HO_2 concentrations in the upper troposphere during the NASA/ST...
ER-2 aircraft observations of OH and HO_2 concentrations in the upper troposphere during the NASA/ST...
A summary of the first order scientific conclusions that emerged from the research done under this g...
In situ measurements of hydrogen, nitrogen, and chlorine radicals obtained in the lower stratosphere...
In situ measurements of hydrogen, nitrogen, and chlorine radicals obtained through sunrise and sunse...
In situ measurements of hydrogen, nitrogen, and chlorine radicals obtained through sunrise and sunse...
Measurements of the ratio OH/HO_2, NO, O_3, ClO, and BrO were obtained at altitudes from 15–20 km an...
Measurements of the ratio OH/HO_2, NO, O_3, ClO, and BrO were obtained at altitudes from 15–20 km an...
Extensive airborne measurements of the reactive nitrogen reservoir (NO_(y)) and its component nitric...
Using observations from balloon-borne instruments and aircraft-borne instruments the investigation a...
The response of ClO concentrations to changes in NO_2 concentrations has been inferred from simultan...
The response of ClO concentrations to changes in NO_2 concentrations has been inferred from simultan...
Recent studies using NO, NO(y), OH and HO2 (HO(X)) observations have postulated acetone and convecti...
Extensive airborne measurements of the reactive nitrogen reservoir (NOy) and its component nitric ox...
The objective of this research was to gain a more thorough understanding of the atmospheric processe...
ER-2 aircraft observations of OH and HO_2 concentrations in the upper troposphere during the NASA/ST...
ER-2 aircraft observations of OH and HO_2 concentrations in the upper troposphere during the NASA/ST...
A summary of the first order scientific conclusions that emerged from the research done under this g...