Add to ORKGThe palladium-catalyzed decarboxylative allylic alkylation of diastereomeric β-ketoesters derived from 4-tert-butylcyclohexanone is described. These experiments were performed to elucidate our understanding of stereoablative enantioconvergent catalysis. A detailed analysis of the product distribution, including stereochemical outcome of the products, is included. These studies also reveal an interesting example of selectivity that is governed by competing modes of substrate and catalyst control
No strain, no gain! The first transition metal-catalyzed enantioselective α-alkylation of cyclobutan...
Caught in the act: A series of unique η1-allyl palladium complexes of four-membered cyclic systems b...
Palladium-catalyzed asymmetric allylic alkylation has become a large and important field for chemica...
A stereochemical test has been used to probe the mechanism of decarboxylative allylation. This probe...
α-Quaternary ketones are accessed through novel enantioselective alkylations of allyl and propargyl ...
Eeny, meeny, miny … enaminones! Lactams and imides have been shown to consistently provide enantiose...
The development of (trimethylsilyl)ethyl ester protected enolates is reported. The application of th...
The first general method for the enantioselective construction of all-carbon quaternary centers on c...
The first highly enantioselective iridium-catalyzed allylic alkylation providing access to products ...
The development of the first enantio-, diastereo-, and regioselective iridium-catalyzed allylic alky...
We report a divergent and modular protocol for the preparation of acyclic molecular frameworks conta...
This research project focused on the investigation of the palladium-catalysed decarboxylative asymme...
Our group has a long-standing interest in Pd or Ru-catalyzed decarboxylative coupling reactions. It ...
General homogeneous conditions for the palladium-catalyzed synthesis of carbonyl compounds with tert...
This document is the Accepted Manuscript version of a Published Work that appeared in final form in ...
No strain, no gain! The first transition metal-catalyzed enantioselective α-alkylation of cyclobutan...
Caught in the act: A series of unique η1-allyl palladium complexes of four-membered cyclic systems b...
Palladium-catalyzed asymmetric allylic alkylation has become a large and important field for chemica...
A stereochemical test has been used to probe the mechanism of decarboxylative allylation. This probe...
α-Quaternary ketones are accessed through novel enantioselective alkylations of allyl and propargyl ...
Eeny, meeny, miny … enaminones! Lactams and imides have been shown to consistently provide enantiose...
The development of (trimethylsilyl)ethyl ester protected enolates is reported. The application of th...
The first general method for the enantioselective construction of all-carbon quaternary centers on c...
The first highly enantioselective iridium-catalyzed allylic alkylation providing access to products ...
The development of the first enantio-, diastereo-, and regioselective iridium-catalyzed allylic alky...
We report a divergent and modular protocol for the preparation of acyclic molecular frameworks conta...
This research project focused on the investigation of the palladium-catalysed decarboxylative asymme...
Our group has a long-standing interest in Pd or Ru-catalyzed decarboxylative coupling reactions. It ...
General homogeneous conditions for the palladium-catalyzed synthesis of carbonyl compounds with tert...
This document is the Accepted Manuscript version of a Published Work that appeared in final form in ...
No strain, no gain! The first transition metal-catalyzed enantioselective α-alkylation of cyclobutan...
Caught in the act: A series of unique η1-allyl palladium complexes of four-membered cyclic systems b...
Palladium-catalyzed asymmetric allylic alkylation has become a large and important field for chemica...