Add to ORKGAn iron diphosphineborane platform that was previously reported to facilitate a high degree of N_2 functionalization is herein shown to effect reductive CO coupling. Disilylation of an iron dicarbonyl precursor furnishes a structurally unprecedented iron dicarbyne complex. Several complexes related to this process are also characterized which allows for a comparative analysis of their respective Fe–B and Fe–C bonding. Facile hydrogenation of the iron dicarbyne at ambient temperature and 1 atm H_2 results in release of a CO-derived olefin
The unique active site of [FeFe]-hydrogenase has inspired over 300 small molecule models derived fro...
Binding of N₂ by the FeMo-cofactor of nitrogenase is believed to occur after transfer of 4 e⁻ and 4 ...
This paper describes the reductive hydrogenolysis of a low-spin (S = 1/2) iron(III) imide. Pseudotet...
An iron diphosphineborane platform that was previously reported to facilitate a high degree of N_2 f...
An iron diphosphineborane platform that was previously reported to facilitate a high degree of N<sub...
THF solutions of a new iron(I) source, [PhBP^(CH2_Cy_3)]Fe ([PhBP^(CH_2Cy_3)] = [PhBP(CH_2P(CH_2Cy)_...
One of the emerging challenges associated with developing robust synthetic nitrogen fixation catalys...
The prototypical reactivity profiles of transition metal dihydrogen complexes (M‐H₂) are well‐charac...
The E‒H bond activation chemistry of tris-phosophino-iron and -cobalt metallaboratranes is discussed...
One of the major challenges associated with developing molecular Fischer–Tropsch catalysts is the de...
During a search for conditions appropriate for Pt-catalyzed CO reduction using dihydrogen directly, ...
We describe the synthesis of a cobalt(I)–N2 complex (2) supported by a meridional bis-phosphino-bory...
The chemistry of diiron complexes has seen a recent renaissance, due to the prominent role played by...
The work described in this thesis emphasizes accessing novel reactivity patterns in the activation o...
Synthetic diiron compounds of the general formula Fe2(μ-S2R)(CO)n(L)6−n (R = alkyl or aromatic group...
The unique active site of [FeFe]-hydrogenase has inspired over 300 small molecule models derived fro...
Binding of N₂ by the FeMo-cofactor of nitrogenase is believed to occur after transfer of 4 e⁻ and 4 ...
This paper describes the reductive hydrogenolysis of a low-spin (S = 1/2) iron(III) imide. Pseudotet...
An iron diphosphineborane platform that was previously reported to facilitate a high degree of N_2 f...
An iron diphosphineborane platform that was previously reported to facilitate a high degree of N<sub...
THF solutions of a new iron(I) source, [PhBP^(CH2_Cy_3)]Fe ([PhBP^(CH_2Cy_3)] = [PhBP(CH_2P(CH_2Cy)_...
One of the emerging challenges associated with developing robust synthetic nitrogen fixation catalys...
The prototypical reactivity profiles of transition metal dihydrogen complexes (M‐H₂) are well‐charac...
The E‒H bond activation chemistry of tris-phosophino-iron and -cobalt metallaboratranes is discussed...
One of the major challenges associated with developing molecular Fischer–Tropsch catalysts is the de...
During a search for conditions appropriate for Pt-catalyzed CO reduction using dihydrogen directly, ...
We describe the synthesis of a cobalt(I)–N2 complex (2) supported by a meridional bis-phosphino-bory...
The chemistry of diiron complexes has seen a recent renaissance, due to the prominent role played by...
The work described in this thesis emphasizes accessing novel reactivity patterns in the activation o...
Synthetic diiron compounds of the general formula Fe2(μ-S2R)(CO)n(L)6−n (R = alkyl or aromatic group...
The unique active site of [FeFe]-hydrogenase has inspired over 300 small molecule models derived fro...
Binding of N₂ by the FeMo-cofactor of nitrogenase is believed to occur after transfer of 4 e⁻ and 4 ...
This paper describes the reductive hydrogenolysis of a low-spin (S = 1/2) iron(III) imide. Pseudotet...