Add to ORKGThe dianionic oxo ligand occupies a very special place in coordination chemistry, owing to its ability to donate π electrons to stabilize high oxidation states of metals. The ligand field theory of multiple bonding in oxo-metal ions, which was formulated in Copenhagen 50 years ago, predicts that there must be an "oxo wall" between Fe-Ru-Os and Co-Rh-Ir in the periodic table. In this tribute to Carl Ballhausen, we review this early work as well as new developments in the field. In particular, we discuss the electronic structures of beyond-the-wall (groups 9 and 10) complexes containing metals multiply bonded to O- and N-donor ligands
Bridged superoxo and peroxodecaamminedicobalt complexes have been investigated using electronic roo...
This is a review of publications concerning the results of X-ray analysis of single crystals and spe...
The nature of multiple bonding involving transition metal atoms has been explored via photoelectron ...
The dianionic oxo ligand occupies a very special place in coordination chemistry, owing to its abil...
The dianionic oxo ligand occupies a very special place in coordination chem., owing to its ability t...
The dianionic oxo ligand occupies a very special place in coordination chem., owing to its ability t...
The electronic structures of cobalt complexes containing O2 units as ligands have been investigated...
Despite their isoelectronic properties, fluoro and oxo ligands exhibit completely different chemical...
We have employed computational methods based on density functional theory to elucidate the effects o...
Metal-oxos are active intermediates in reactions crit. for life on Planet Earth, water oxidn. to oxy...
Ru=O complexes have been demonstrated to be competent oxidants for oxidation of saturated hydrocarbo...
The search for more economical and environmentally friendly oxidation catalysts for organic function...
Gas-phase photoelectron spectroscopy was utilized to study a series of metal-metal bonded complexes....
Three sets of metal-metal bonded systems of the form M₂(L ͡ L)₄ have been studied by gas-phase ultra...
The synthesis of the Lewis acid–base adducts of B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub> and BF<su...
Bridged superoxo and peroxodecaamminedicobalt complexes have been investigated using electronic roo...
This is a review of publications concerning the results of X-ray analysis of single crystals and spe...
The nature of multiple bonding involving transition metal atoms has been explored via photoelectron ...
The dianionic oxo ligand occupies a very special place in coordination chemistry, owing to its abil...
The dianionic oxo ligand occupies a very special place in coordination chem., owing to its ability t...
The dianionic oxo ligand occupies a very special place in coordination chem., owing to its ability t...
The electronic structures of cobalt complexes containing O2 units as ligands have been investigated...
Despite their isoelectronic properties, fluoro and oxo ligands exhibit completely different chemical...
We have employed computational methods based on density functional theory to elucidate the effects o...
Metal-oxos are active intermediates in reactions crit. for life on Planet Earth, water oxidn. to oxy...
Ru=O complexes have been demonstrated to be competent oxidants for oxidation of saturated hydrocarbo...
The search for more economical and environmentally friendly oxidation catalysts for organic function...
Gas-phase photoelectron spectroscopy was utilized to study a series of metal-metal bonded complexes....
Three sets of metal-metal bonded systems of the form M₂(L ͡ L)₄ have been studied by gas-phase ultra...
The synthesis of the Lewis acid–base adducts of B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub> and BF<su...
Bridged superoxo and peroxodecaamminedicobalt complexes have been investigated using electronic roo...
This is a review of publications concerning the results of X-ray analysis of single crystals and spe...
The nature of multiple bonding involving transition metal atoms has been explored via photoelectron ...