We report the development of ruthenium-based metathesis catalysts with chelating N-heterocyclic carbene (NHC) ligands that catalyze highly Z-selective olefin metathesis. A very simple and convenient procedure for the synthesis of such catalysts has been developed. Intramolecular C–H bond activation of the NHC ligand, promoted by anion ligand substitution, forms the appropriate chelate for stereocontrolled olefin metathesis
International audienceA ruthenium catalyst for Z-selective olefin metathesis has been synthesized fr...
Several new C–H-activated ruthenium catalysts for <i>Z</i>-selective olefin metathesis have been syn...
Several new C–H-activated ruthenium catalysts for <i>Z</i>-selective olefin metathesis have been syn...
A novel chelated ruthenium-based metathesis catalyst bearing an N-2,6-diisopropylphenyl group is rep...
A series of ruthenium catalysts bearing five-membered chelating NHC architectures that exhibit very ...
A series of cyclometalated Z-selective ruthenium olefin metathesis catalysts with alterations to the...
A novel method to effect the salt metathesis and C-H activation of ruthenium-based, Z-selective meta...
A novel method to effect the salt metathesis and C-H activation of ruthenium-based, Z-selective meta...
The recent development of a class of Z-selective ruthenium metathesis catalysts containing a crucial...
Our group has recently reported a series of ruthenium-based metathesis catalysts that contain a che...
The cross-metathesis of terminal olefins using a novel ruthenium catalyst results in excellent selec...
Chelated ruthenium catalysts can facilitate highly chemoselective olefin metathesis. Terminal and in...
Publications about olefin metathesis will generally discuss how the discovery and development of wel...
A ruthenium complex bearing an “anti-Bredt” N-heterocyclic carbene was synthesized, characterized an...
International audienceA ruthenium catalyst for Z-selective olefin metathesis has been synthesized fr...
International audienceA ruthenium catalyst for Z-selective olefin metathesis has been synthesized fr...
Several new C–H-activated ruthenium catalysts for <i>Z</i>-selective olefin metathesis have been syn...
Several new C–H-activated ruthenium catalysts for <i>Z</i>-selective olefin metathesis have been syn...
A novel chelated ruthenium-based metathesis catalyst bearing an N-2,6-diisopropylphenyl group is rep...
A series of ruthenium catalysts bearing five-membered chelating NHC architectures that exhibit very ...
A series of cyclometalated Z-selective ruthenium olefin metathesis catalysts with alterations to the...
A novel method to effect the salt metathesis and C-H activation of ruthenium-based, Z-selective meta...
A novel method to effect the salt metathesis and C-H activation of ruthenium-based, Z-selective meta...
The recent development of a class of Z-selective ruthenium metathesis catalysts containing a crucial...
Our group has recently reported a series of ruthenium-based metathesis catalysts that contain a che...
The cross-metathesis of terminal olefins using a novel ruthenium catalyst results in excellent selec...
Chelated ruthenium catalysts can facilitate highly chemoselective olefin metathesis. Terminal and in...
Publications about olefin metathesis will generally discuss how the discovery and development of wel...
A ruthenium complex bearing an “anti-Bredt” N-heterocyclic carbene was synthesized, characterized an...
International audienceA ruthenium catalyst for Z-selective olefin metathesis has been synthesized fr...
International audienceA ruthenium catalyst for Z-selective olefin metathesis has been synthesized fr...
Several new C–H-activated ruthenium catalysts for <i>Z</i>-selective olefin metathesis have been syn...
Several new C–H-activated ruthenium catalysts for <i>Z</i>-selective olefin metathesis have been syn...