Add to ORKGThe preparation and synthetic applications of benzoquinone monoketal-derived N-tert-butanesulfinyl imines is described. These synthetically versatile intermediates undergo highly diastereoselective 1,2-addition reactions with organometallic reagents to provide 4-aminocyclohexadienones in good yields. The utility of this methodology is demonstrated in a six-step enantioselective synthesis of (–)-3-demethoxyerythratidinone
The reaction of chiral N-tert-butanesulfinyl aldimines with β-keto acids under basic conditions at r...
A formal, one-pot, [4+4] cyclization pathway for the generation of 8-member sultams via in-situ gene...
The synthesis of novel δ-sultam scaffolds utilizing one-pot, three-component reactions of 1,3-dicarb...
The preparation and synthetic applications of benzoquinone monoketal-derived N-tert-butanesulfinyl i...
(+)-Stephadiamine is an unusual alkaloid isolated from the vine Stephania japonica. It features a no...
The addition of a Grignard reagent to both enantiomeric N-tert-butanesulfinyl imines derived from 3-...
Chapter one describes how synthetic strategy has enabled an investigation of the reactivities of new...
An enantioselective total synthesis of the diterpenoid natural product (+)-salvileucalin B is repo...
The first direct enantioselective organocatalytic intramolecular Diels−Alder reaction has been accom...
A convergent and enantioselective synthesis of the natural product amurensinine is described. The sy...
Enantioselective Pd-catalyzed allylic alkylations of dihydropyrido[1,2-a]indolone (DHPI) substrates ...
A total synthesis of the racemic modification, (±)-2, of the tazettine-type alkaloid 3-O-demethylmac...
A catalytic enantioselective approach to the eudesmane sesquiterpenoids is reported. The strategic u...
We describe the first application of our methodology for heterodimerization via diazene fragmentatio...
A tandem rhodium-catalyzed Bamford−Stevens/Claisen rearrangement is presented. The tandem reaction u...
The reaction of chiral N-tert-butanesulfinyl aldimines with β-keto acids under basic conditions at r...
A formal, one-pot, [4+4] cyclization pathway for the generation of 8-member sultams via in-situ gene...
The synthesis of novel δ-sultam scaffolds utilizing one-pot, three-component reactions of 1,3-dicarb...
The preparation and synthetic applications of benzoquinone monoketal-derived N-tert-butanesulfinyl i...
(+)-Stephadiamine is an unusual alkaloid isolated from the vine Stephania japonica. It features a no...
The addition of a Grignard reagent to both enantiomeric N-tert-butanesulfinyl imines derived from 3-...
Chapter one describes how synthetic strategy has enabled an investigation of the reactivities of new...
An enantioselective total synthesis of the diterpenoid natural product (+)-salvileucalin B is repo...
The first direct enantioselective organocatalytic intramolecular Diels−Alder reaction has been accom...
A convergent and enantioselective synthesis of the natural product amurensinine is described. The sy...
Enantioselective Pd-catalyzed allylic alkylations of dihydropyrido[1,2-a]indolone (DHPI) substrates ...
A total synthesis of the racemic modification, (±)-2, of the tazettine-type alkaloid 3-O-demethylmac...
A catalytic enantioselective approach to the eudesmane sesquiterpenoids is reported. The strategic u...
We describe the first application of our methodology for heterodimerization via diazene fragmentatio...
A tandem rhodium-catalyzed Bamford−Stevens/Claisen rearrangement is presented. The tandem reaction u...
The reaction of chiral N-tert-butanesulfinyl aldimines with β-keto acids under basic conditions at r...
A formal, one-pot, [4+4] cyclization pathway for the generation of 8-member sultams via in-situ gene...
The synthesis of novel δ-sultam scaffolds utilizing one-pot, three-component reactions of 1,3-dicarb...