Stable carbenes react with [Fe(cot)_2] in very different ways. Whereas the classical N-heterocyclic carbenes induce the formation of tetra- and trimetallic iron clusters, abnormal NHCs and carbocyclic carbenes (BACs) form mono- and bimetallic iron complexes. Cyclic (alkyl)(amino)carbenes (CAACs) react with [Fe(cot)_2] in a completely different manner, namely through outersphere [4+1] cycloaddition
[[abstract]]An N-alkyl imidazole bearing a neutral {Fe(NO)2}10 dinitrosyliron complex (DNIC) when tr...
International audienceMetallotropism of the M[N(SiMe3)2]2 metal fragment in the tautomeric system IA...
Carbenes have played an important role as reactive intermediates in synthetic organic chemistry for ...
Stable carbenes react with [Fe(cot)_2] in very different ways. Whereas the classical N-heterocyclic ...
Compared with the enormous arsenal of catalysts used to produce organic compounds, complementary spe...
The synthesis, structures, and reactivity of dinuclear Fe<sup>0</sup> complexes of N-heterocyclic ca...
Despite their promising metal–ligand cooperative reactivity, PCcarbeneP pincer ligands are rarely r...
A sterically demanding seven-membered expanded ring N-heterocyclic carbene (NHC) ligand allows acces...
Reaction of FeCl<sub>2</sub> with the chelating bis-<i>N</i>-heterocyclic carbene (NHC) bis-(<i>N</i...
This review compiles the advances achieved in our laboratories using abnormal and less heteroatom-st...
The molecular structures, chemical bonding and magnetochemistry of the three-coordinate iron(II) NHC...
All it's CAACed up to be! Cyclic (alkyl)(amino)carbenes (CAACs) can be used as ligands for olefin me...
We gratefully acknowledge VLAIO (SBO project CO2PERATE), King Saud University (Distinguished Scienti...
Addition of cyanide ions to the alkynyl(methoxy)carbene complexes [Fe2{μ-CN(Me)(R)}(μ-CO)...
[[abstract]]An N-alkyl imidazole bearing a neutral {Fe(NO)2}10 dinitrosyliron complex (DNIC) when tr...
International audienceMetallotropism of the M[N(SiMe3)2]2 metal fragment in the tautomeric system IA...
Carbenes have played an important role as reactive intermediates in synthetic organic chemistry for ...
Stable carbenes react with [Fe(cot)_2] in very different ways. Whereas the classical N-heterocyclic ...
Compared with the enormous arsenal of catalysts used to produce organic compounds, complementary spe...
The synthesis, structures, and reactivity of dinuclear Fe<sup>0</sup> complexes of N-heterocyclic ca...
Despite their promising metal–ligand cooperative reactivity, PCcarbeneP pincer ligands are rarely r...
A sterically demanding seven-membered expanded ring N-heterocyclic carbene (NHC) ligand allows acces...
Reaction of FeCl<sub>2</sub> with the chelating bis-<i>N</i>-heterocyclic carbene (NHC) bis-(<i>N</i...
This review compiles the advances achieved in our laboratories using abnormal and less heteroatom-st...
The molecular structures, chemical bonding and magnetochemistry of the three-coordinate iron(II) NHC...
All it's CAACed up to be! Cyclic (alkyl)(amino)carbenes (CAACs) can be used as ligands for olefin me...
We gratefully acknowledge VLAIO (SBO project CO2PERATE), King Saud University (Distinguished Scienti...
Addition of cyanide ions to the alkynyl(methoxy)carbene complexes [Fe2{μ-CN(Me)(R)}(μ-CO)...
[[abstract]]An N-alkyl imidazole bearing a neutral {Fe(NO)2}10 dinitrosyliron complex (DNIC) when tr...
International audienceMetallotropism of the M[N(SiMe3)2]2 metal fragment in the tautomeric system IA...
Carbenes have played an important role as reactive intermediates in synthetic organic chemistry for ...