The preparation and spectroscopic properties of a series of metallocorroles with polar head groups CHO and CH=C(CN)(COOH) are reported, as well as the X-ray crystal structure of 5,10,15-tris(pentafluorophenyl)corrolatoaluminium(III)bispyridine (triclinic space group (P-1) with unit cell parameters: a = 9.426(1) Å; b = 13.202(1) Å; c = 19.936(1) Å; α = 74.19(1)°; β = 78.47(1)°; γ = 75.75(1)°; V = 2289.57(8) Å^3). Amphiphilic aluminium(III) and gallium(III) corroles exhibit electronic absorption (Soret peaks between 410 and 448 nm; Q-bands between 584 and 638 nm) and fluorescence (band maxima between 634 and 706 nm) at lower energies than their hydrophobic analogs
Facile procedures were developed for selective iodination of aluminum and gallium corroles; crystall...
Transition-metal complexes of 2,3,7,8,12,13,17,18-octamethylcorrole (H 3omc) have been prepared in h...
The transition metal complexes of the non-innocent, electron-rich corrole macrocycle are discussed....
The development of efficient synthetic methodologies and post-functionalization procedures gave acce...
The development of efficient synthetic methodologies and post-functionalization procedures gave acce...
High quantum yields are found for the prototype metallocorrole 1, which is readily prepared from GaC...
In aqueous media, hydrophobic metallocorroles form nanoparticles that are potential theranostic anti...
Three mono-CN ligated anionic cobalt A3-triarylcorroles were synthesized and investigated as to thei...
none9si5,10,15-Triaryltetrabenzocorrole complexes of aluminum, gallium, germanium, and phosphorus we...
The coordination chemistry of corrole is one of the most intriguing aspects of this contracted porph...
X-ray structures of gold corroles, which are still rather uncommon, afford significant insights into...
International audienceThree mono-CN ligated anionic cobalt A3-triarylcorroles were synthesized and i...
Facile procedures were developed for selective iodination of aluminum and gallium corroles; crystall...
Transition-metal complexes of 2,3,7,8,12,13,17,18-octamethylcorrole (H 3omc) have been prepared in h...
The transition metal complexes of the non-innocent, electron-rich corrole macrocycle are discussed....
The development of efficient synthetic methodologies and post-functionalization procedures gave acce...
The development of efficient synthetic methodologies and post-functionalization procedures gave acce...
High quantum yields are found for the prototype metallocorrole 1, which is readily prepared from GaC...
In aqueous media, hydrophobic metallocorroles form nanoparticles that are potential theranostic anti...
Three mono-CN ligated anionic cobalt A3-triarylcorroles were synthesized and investigated as to thei...
none9si5,10,15-Triaryltetrabenzocorrole complexes of aluminum, gallium, germanium, and phosphorus we...
The coordination chemistry of corrole is one of the most intriguing aspects of this contracted porph...
X-ray structures of gold corroles, which are still rather uncommon, afford significant insights into...
International audienceThree mono-CN ligated anionic cobalt A3-triarylcorroles were synthesized and i...
Facile procedures were developed for selective iodination of aluminum and gallium corroles; crystall...
Transition-metal complexes of 2,3,7,8,12,13,17,18-octamethylcorrole (H 3omc) have been prepared in h...
The transition metal complexes of the non-innocent, electron-rich corrole macrocycle are discussed....