Add to ORKGThe recent study of diphenyl butadiene (DPB) in supersonic jets and in solution by Shepanski et al.(1) and by Courtney and Felming(2), respectively, provides an opportunity to compare the isomerization rates measured in the isolated molecule (jet) with those measured at very low viscosity in solution. These comparisons should shed light on the vibrational energy flows between “optical” and “reactive” modes in the isolated molecule and on the connection between activated, friction dependent, models of barrier crossing in solution,(3-5) and statistical RRK (or RRKM) theories of gas phase unimolecular reactions(6)
Condensed-phase alkoxy (RO) radicals can undergo unimolecular (e.g., intramolecular H atom abstracti...
Data on quasi-unimolecular reactions have usually been compared with theoretical equations based on ...
The dynamics of collisionless intramolecular vibrational-energy redistribution (IVR), bond breakage,...
Rates of isomerization of electronically excited trans-stilbene and of the dissociation of isoquinol...
Author Institution: Department of Chemistry and The James Franck Institute, The University of Chicag...
This work is primarily concerned with the development of models for the quantum dynamics of unimolec...
Unimolecular reaction rate constant measurements on systems with well known total energy contents pe...
In a letter under the above title in NATURE of May 12, the interchange of energy between solvent and...
Interstellar chemistry has been a growing field over the last several decades. There is particular ...
Intermolecular energy transfer of highly excited polyatomic molecules plays an important role in man...
Using picosecond excitation in a supersonic jet, we present a full account of our earlier report on ...
How vibrational energy flows in molecules has recently become much better understood through the joi...
Recent advances in the dynamics of photochemical isomerization reactions in solution are reviewed. T...
Systematic measurements were made on the deactivation rate constants (k(Delta)) of O-2(a(1)Delta) by...
The work presented here is the first in a series of studies that use a molecular beam scattering tec...
Condensed-phase alkoxy (RO) radicals can undergo unimolecular (e.g., intramolecular H atom abstracti...
Data on quasi-unimolecular reactions have usually been compared with theoretical equations based on ...
The dynamics of collisionless intramolecular vibrational-energy redistribution (IVR), bond breakage,...
Rates of isomerization of electronically excited trans-stilbene and of the dissociation of isoquinol...
Author Institution: Department of Chemistry and The James Franck Institute, The University of Chicag...
This work is primarily concerned with the development of models for the quantum dynamics of unimolec...
Unimolecular reaction rate constant measurements on systems with well known total energy contents pe...
In a letter under the above title in NATURE of May 12, the interchange of energy between solvent and...
Interstellar chemistry has been a growing field over the last several decades. There is particular ...
Intermolecular energy transfer of highly excited polyatomic molecules plays an important role in man...
Using picosecond excitation in a supersonic jet, we present a full account of our earlier report on ...
How vibrational energy flows in molecules has recently become much better understood through the joi...
Recent advances in the dynamics of photochemical isomerization reactions in solution are reviewed. T...
Systematic measurements were made on the deactivation rate constants (k(Delta)) of O-2(a(1)Delta) by...
The work presented here is the first in a series of studies that use a molecular beam scattering tec...
Condensed-phase alkoxy (RO) radicals can undergo unimolecular (e.g., intramolecular H atom abstracti...
Data on quasi-unimolecular reactions have usually been compared with theoretical equations based on ...
The dynamics of collisionless intramolecular vibrational-energy redistribution (IVR), bond breakage,...