Add to ORKGThe Fe(TPA) (TPA = tris(pyridyl-2-methyl)amine) class of non-haem Fe catalysts is proposed to carry out selective hydrocarbon oxidations through the generation of high-valent iron species. Using ambient mass spectrometry, we obtain direct evidence for the formation of an FeV(O)(OH) species under catalytic conditions. In addition, 18O-labelling suggests that this FeV(O)(OH) species serves as the active oxidant in hydrocarbon oxidation catalysis
International audienceHigh-valent oxo-metal complexes are involved in key biochemical processes of s...
International audienceHigh-valent oxo-metal complexes are involved in key biochemical processes of s...
A detailed mechanistic study of the hydroxylation of alkane CH bonds using H2O2 by a family of monon...
Oxo-transfer chemistry mediated by iron underpins many biological processes and today is emerging as...
Oxo-transfer chemistry mediated by iron underpins many biological processes and today is emerging as...
Synthetically useful hydrocarbon oxidations are catalysed by bio-inspired non-heme iron complexes us...
FeV(O)(OH) species have long been proposed to play a key role in a wide range of biomimetic and enzy...
Inspired by the remarkable chemistry of the family of Rieske oxygenase enzymes, nonheme iron complex...
Herein, we report the EPR spectroscopic study of the bioinspired catalyst systems for selective hydr...
Oxidative C-H bond activation, is a transformation of fundamental and practical interest, particular...
Herein, we report the EPR spectroscopic study of the bioinspired catalyst systems for selective hydr...
Hydrocarbon oxidations by bio-inspired nonheme iron catalysts and H<sub>2</sub>O<sub>2</sub> have be...
Very recently, in situ cryospray-assisted variable temperature mass spectrometry (VT-MS) has been us...
The development of efficient and selective hydrocarbon oxidation processes with low environmental im...
International audienceHigh-valent oxo-metal complexes are involved in key biochemical processes of s...
International audienceHigh-valent oxo-metal complexes are involved in key biochemical processes of s...
International audienceHigh-valent oxo-metal complexes are involved in key biochemical processes of s...
A detailed mechanistic study of the hydroxylation of alkane CH bonds using H2O2 by a family of monon...
Oxo-transfer chemistry mediated by iron underpins many biological processes and today is emerging as...
Oxo-transfer chemistry mediated by iron underpins many biological processes and today is emerging as...
Synthetically useful hydrocarbon oxidations are catalysed by bio-inspired non-heme iron complexes us...
FeV(O)(OH) species have long been proposed to play a key role in a wide range of biomimetic and enzy...
Inspired by the remarkable chemistry of the family of Rieske oxygenase enzymes, nonheme iron complex...
Herein, we report the EPR spectroscopic study of the bioinspired catalyst systems for selective hydr...
Oxidative C-H bond activation, is a transformation of fundamental and practical interest, particular...
Herein, we report the EPR spectroscopic study of the bioinspired catalyst systems for selective hydr...
Hydrocarbon oxidations by bio-inspired nonheme iron catalysts and H<sub>2</sub>O<sub>2</sub> have be...
Very recently, in situ cryospray-assisted variable temperature mass spectrometry (VT-MS) has been us...
The development of efficient and selective hydrocarbon oxidation processes with low environmental im...
International audienceHigh-valent oxo-metal complexes are involved in key biochemical processes of s...
International audienceHigh-valent oxo-metal complexes are involved in key biochemical processes of s...
International audienceHigh-valent oxo-metal complexes are involved in key biochemical processes of s...
A detailed mechanistic study of the hydroxylation of alkane CH bonds using H2O2 by a family of monon...