Using 293 K diffractometer intensity data, the structures of [H3N(CH2)3NH3]TeCl6 and [H3N(CH2)3NH3]SnCl6 have been determined by single crystal X-ray technique and refined to a final of 0.027 and 0,029, respectively. The yellow crystals of the tellurate are orthorhombic (space group Pnma) with a = 22.952(2), b = 7.5414(4), c - 7.801(1) Å and Z = 4. This structure contains distorted TeCl62- octahedra (distances Te - Cl min. 2.426(1), max. 2.672(1) Å ) with approximate 2mm point symmetry. In contrast, the SnCl62- ion in the second title com pound is octahedral with only small deviations from m 3m symmetry (distances Sn -Cl mean: 2.438(3) Ä ). The colourless crystals of this tin com pound are orthorhombic (space group Pnma) with a - 17.6082(9)...
In each of the title compounds, R[Ph(Cl)C=(H)C]TeCl(2), R = nBu (1) and Ph (2), the primary geometry...
International audienceWe developed a simple method based on pure geometrical concepts to localize lo...
The primary theme of this research was the characterisation of new and novel organo-tellurium comple...
Linear three-centre systems of sixth-group atoms occur in the triselenocyanate ion and in a series o...
Using 293 K diffractometer intensity data, the crystal structures of (NH4)2SeBr6 (1) and [H3N(CH2)3N...
Complex transition metals oxyhalides containing a lone pair element, such as tellurium (IV), form an...
Both title compounds show an antifluorite-like arrangement of (CH3)4N+ cations and TeCl6 2- anions. ...
In an attempt to determine the crystal and molecular structure of previously reported [TeCl2(dmit)4]...
The crystal and molecular structures of trans-2-ethoxy-cyclohexyltellurium(IV) trichloride (1), tric...
The asymmetric unit of the title compound, C18H15ClTe, contains two molecules which are in inverted ...
[[abstract]]The crystal and molecular structure of tetraphenyltellurium-benzene (1/8) has been deter...
A survey of the crystallographic literature of tellurium(II)/(IV) 1,1-dithiolates(dithiocarbamate,xa...
The luminescence of the following compounds is reported: Cs2TeCl6 and Rb2TeBr6, both with undistorte...
The electronic spectra of the octahedral Tecl_6^(2-) and TeBr+6^(2-) complexes are reported and assi...
The product isolated as colourless crystals from the reaction system TeCl4-SbCl5-18-crown-6-MeCN has...
In each of the title compounds, R[Ph(Cl)C=(H)C]TeCl(2), R = nBu (1) and Ph (2), the primary geometry...
International audienceWe developed a simple method based on pure geometrical concepts to localize lo...
The primary theme of this research was the characterisation of new and novel organo-tellurium comple...
Linear three-centre systems of sixth-group atoms occur in the triselenocyanate ion and in a series o...
Using 293 K diffractometer intensity data, the crystal structures of (NH4)2SeBr6 (1) and [H3N(CH2)3N...
Complex transition metals oxyhalides containing a lone pair element, such as tellurium (IV), form an...
Both title compounds show an antifluorite-like arrangement of (CH3)4N+ cations and TeCl6 2- anions. ...
In an attempt to determine the crystal and molecular structure of previously reported [TeCl2(dmit)4]...
The crystal and molecular structures of trans-2-ethoxy-cyclohexyltellurium(IV) trichloride (1), tric...
The asymmetric unit of the title compound, C18H15ClTe, contains two molecules which are in inverted ...
[[abstract]]The crystal and molecular structure of tetraphenyltellurium-benzene (1/8) has been deter...
A survey of the crystallographic literature of tellurium(II)/(IV) 1,1-dithiolates(dithiocarbamate,xa...
The luminescence of the following compounds is reported: Cs2TeCl6 and Rb2TeBr6, both with undistorte...
The electronic spectra of the octahedral Tecl_6^(2-) and TeBr+6^(2-) complexes are reported and assi...
The product isolated as colourless crystals from the reaction system TeCl4-SbCl5-18-crown-6-MeCN has...
In each of the title compounds, R[Ph(Cl)C=(H)C]TeCl(2), R = nBu (1) and Ph (2), the primary geometry...
International audienceWe developed a simple method based on pure geometrical concepts to localize lo...
The primary theme of this research was the characterisation of new and novel organo-tellurium comple...