Reactivity of Cross-Conjugated (pentadienyl)iron Cations: Formation of Diene and Trimethylenemethane Complexes
- Donaldson, William
- Hossain, M. Azad
Publication date
November 1991
DOI Publisher
Elsevier BV ISSN
0040-4039 Citation count (estimate)
6Abstract
The title cations can be generated from the BF3.Et2O mediated ionization of (acetoxymethylene-butadiene)Fe(CO)3 complexes. The cation reacts with carbon nucleophiles predominantly at C-4 to afford (trimethylenemethane)Fe(CO)3 products. The title cations can be generated from the BF3. Et2O mediated ionization of (acetoxymethylenebutadiene) Fe (CO)3 complexes. The cations react with carbon nucleophiles predominantly at C-4 to afford (trimethylenemethane) Fe (CO)3 products
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