The first examples of a class of N-confused tris(pyrazolyl)methane ‘scorpionate’ ligands have been prepared. The magnetic properties of their iron(II) tetrafluoroborate complexes are dictated by changing one substituent per ligand rather than three as is typical for normal scorpionate ligands
A series of iron(II) chloride complexes of pentadentate ligands related to α,α,α′,α′-tetra(pyrazolyl...
Tris(pyrazolyl)methanes (tpms) are a versatile class of ligand consisting of a central carbon atom b...
The computed energy profile of the angular Jahn-Teller distortion that is often shown by high-spin [...
Seven different 2,6-di(1H-pyrazol-1-yl)pyridine ligands were synthesized from 4-cyano-2,6dichloropyr...
The synthesis and coordination chemistry of new classes of scorpionate ligands are discussed, with t...
The influence of ligands on the spin state of a metal ion is of central importance for bioinorganic ...
Three mononuclear iron(II) complexes of the formula [FeII(H2L1-3)2](BF4)2.x(solv.) (H2L1-3 = 2-[5-(R...
The second-generation Janus scorpionate ligand [HB(mtdaMe)3−] containing methyl-mercaptothiadiazolyl...
The influence of ligands on the spin state of a metal ion is of central importance for bioinorganic ...
An understanding of the molecular properties that influence highly-cooperative SCO behavior is criti...
The spin-crossover equilibrium midpoint temperature (T1/2) in [Fe(3-bpp)2]X2 (3-bpp = 2,6-di{pyrazol...
The complexes {Fe[HC(3,5-Me2pz)3]2} (BF4)2 (1), {Fe[HC(pz)3]2}(BF4)2 (2), and {Fe[PhC(pz)2(py)]2}(BF...
The spin crossover behavior of the two [Fe(mtz)(6)](2+) complexes occupying different lattice sites ...
Seven derivatives of [FeL2]2+ (L = 2,4-di{pyrazol-1-yl}-1,3,5-triazine) are all high-spin. DFT calcu...
Two new C-scorpionate ligands with a bis(3,5-dimethylpyrazol-1-yl)methyl group bound to the 3 positi...
A series of iron(II) chloride complexes of pentadentate ligands related to α,α,α′,α′-tetra(pyrazolyl...
Tris(pyrazolyl)methanes (tpms) are a versatile class of ligand consisting of a central carbon atom b...
The computed energy profile of the angular Jahn-Teller distortion that is often shown by high-spin [...
Seven different 2,6-di(1H-pyrazol-1-yl)pyridine ligands were synthesized from 4-cyano-2,6dichloropyr...
The synthesis and coordination chemistry of new classes of scorpionate ligands are discussed, with t...
The influence of ligands on the spin state of a metal ion is of central importance for bioinorganic ...
Three mononuclear iron(II) complexes of the formula [FeII(H2L1-3)2](BF4)2.x(solv.) (H2L1-3 = 2-[5-(R...
The second-generation Janus scorpionate ligand [HB(mtdaMe)3−] containing methyl-mercaptothiadiazolyl...
The influence of ligands on the spin state of a metal ion is of central importance for bioinorganic ...
An understanding of the molecular properties that influence highly-cooperative SCO behavior is criti...
The spin-crossover equilibrium midpoint temperature (T1/2) in [Fe(3-bpp)2]X2 (3-bpp = 2,6-di{pyrazol...
The complexes {Fe[HC(3,5-Me2pz)3]2} (BF4)2 (1), {Fe[HC(pz)3]2}(BF4)2 (2), and {Fe[PhC(pz)2(py)]2}(BF...
The spin crossover behavior of the two [Fe(mtz)(6)](2+) complexes occupying different lattice sites ...
Seven derivatives of [FeL2]2+ (L = 2,4-di{pyrazol-1-yl}-1,3,5-triazine) are all high-spin. DFT calcu...
Two new C-scorpionate ligands with a bis(3,5-dimethylpyrazol-1-yl)methyl group bound to the 3 positi...
A series of iron(II) chloride complexes of pentadentate ligands related to α,α,α′,α′-tetra(pyrazolyl...
Tris(pyrazolyl)methanes (tpms) are a versatile class of ligand consisting of a central carbon atom b...
The computed energy profile of the angular Jahn-Teller distortion that is often shown by high-spin [...