Trispyrazoleborate is a negatively charged facially coordinating tridentate ligand that has been highly researched and used in many metal complexes. The related ligand trispyrazolemethane has not been widely studied due to its difficult synthesis. The objective of this project is to determine the effects of the neutral nature of the trispyrazolemethane on the metal carbonyl complexes of molybdenum and tungsten. Besides the ligand tricarbonyl complex, iodide and hydride derivatives were synthesized. All compounds were characterized with IR and HNMR
Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2001.Includes bibliograp...
A series of tris-alcohol substituted triazamacrocyclic ligands has been prepared, with the purpose o...
M.Sc.This dissertation deals with the syntheses of tridentate (O^N^N) coordination ligands [{2,4-di-...
The scorpionate ligand tris(pyrazolyl)borate (Tp) has contributed to the understanding of coordinati...
A series of known and new seven coordinate molybdenum and tungsten complexes of tris(pyrazolyl)metha...
A family of novel tripodal, tetraamine (N4) ligands incorporating three heterocyclic donors and ineq...
Tris(pyrazolyl)methane ligands (Tpmx) have been for years a step behind their highly popular boron-a...
Summarization: Reaction of [HB(bdmpz),] , obtained by reaction of 4-benzyl-3,5-dimethylpyrazole (Hbd...
The reaction of new binuclear hexadentate diacylhydrazone ligands with the metal precursor (MoO2(aca...
Tris(pyrazolyl)methanes are the neutral analogues of the widely exploited and highly useful tris(pyr...
Tripodal ligand systems are of key interest in the synthesis of new and promising metal complexes si...
International audienceThe tris(1‐pyrazolyl)methanesulfonate lithium salt Li(Tpms) [Tpms = SO3C(pz)3–...
Five new complexes, [M(CO)5(salmsh)] (M=Cr;1,Mo;2,W;3), [Re(CO)4Br(salmsh)], 4, and [Mn(CO)3 (salmsh...
The substituted ligands Me3SiC(pz)3 and Me 3SiOCH2C(pz)3 (2) have been prepared starting from HC(pz)...
The first group 3 organometallic compounds containing the tris(3,5-dimethylpyrazolyl)methane (HC(Me2...
Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2001.Includes bibliograp...
A series of tris-alcohol substituted triazamacrocyclic ligands has been prepared, with the purpose o...
M.Sc.This dissertation deals with the syntheses of tridentate (O^N^N) coordination ligands [{2,4-di-...
The scorpionate ligand tris(pyrazolyl)borate (Tp) has contributed to the understanding of coordinati...
A series of known and new seven coordinate molybdenum and tungsten complexes of tris(pyrazolyl)metha...
A family of novel tripodal, tetraamine (N4) ligands incorporating three heterocyclic donors and ineq...
Tris(pyrazolyl)methane ligands (Tpmx) have been for years a step behind their highly popular boron-a...
Summarization: Reaction of [HB(bdmpz),] , obtained by reaction of 4-benzyl-3,5-dimethylpyrazole (Hbd...
The reaction of new binuclear hexadentate diacylhydrazone ligands with the metal precursor (MoO2(aca...
Tris(pyrazolyl)methanes are the neutral analogues of the widely exploited and highly useful tris(pyr...
Tripodal ligand systems are of key interest in the synthesis of new and promising metal complexes si...
International audienceThe tris(1‐pyrazolyl)methanesulfonate lithium salt Li(Tpms) [Tpms = SO3C(pz)3–...
Five new complexes, [M(CO)5(salmsh)] (M=Cr;1,Mo;2,W;3), [Re(CO)4Br(salmsh)], 4, and [Mn(CO)3 (salmsh...
The substituted ligands Me3SiC(pz)3 and Me 3SiOCH2C(pz)3 (2) have been prepared starting from HC(pz)...
The first group 3 organometallic compounds containing the tris(3,5-dimethylpyrazolyl)methane (HC(Me2...
Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2001.Includes bibliograp...
A series of tris-alcohol substituted triazamacrocyclic ligands has been prepared, with the purpose o...
M.Sc.This dissertation deals with the syntheses of tridentate (O^N^N) coordination ligands [{2,4-di-...