Self-assembling of poly(allylamine) containing an osmium polypyridil complex (PAOs) alternatively with sodium dodecyl sulfate (SDS) and glucose oxidase (GOx) generates a ternary multilayer system, (PAOs/SDS/PAOs/GOx)n. The introduction of this anionic surfactant allows a sensitive increase of the polyelectrolyte and the enzyme uptake at pH 7.0, enhancing its catalytic behavior in presence of glucose more than 5 times, compared to the system (PAOs/GOx)n constructed at the same pH. The balance between ionic and hydrophobic interactions in the construction of this system is discussed.Fil: Cortez, María Lorena. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Q...
High-power density output in enzymatic fuel cells is a key feature to reduce the size of self-powere...
Graduation date: 2010Functional polymers and proteins at interfaces and surfaces are of fundamental ...
Increasingly used in industrial coatings, polyelectrolytes multilayers (PEMs) are self-assembled sys...
The present study explores the development of mesostructured bioelectrochemical interfaces with accu...
In this work the effects of the self-assembly solvent on the structure and electrochemical behavior ...
Contains fulltext : 10325.pdf (publisher's version ) (Open Access
The strong interaction between a positively charged electroactive polyelectrolyte (polyallylamine de...
High-power density output in enzymatic fuel cells is a key feature to reduce the size of self-powere...
Layer by layer assembly of polyelectrolytes with proteins is a convenient tool for the development o...
Regeneration and reutilization of cofactors remain as the biggest challenge facing the industrial ap...
The cationic polyelectrolyte PVp-S/anionic surfactant SDS and anionic polyelectrolyte P(SPMS-S) S/ca...
We present a new methodology for the generation of discrete molecularly dispersed enzyme− polymer−...
The search for strategies to improve the performance of bioelectrochemical platforms based on supram...
This thesis is focused on the immobilization of a selected biomolecule, Horseradish peroxidase enzym...
The main objective of this PhD thesis was to gain a deep molecular understanding of interactions whi...
High-power density output in enzymatic fuel cells is a key feature to reduce the size of self-powere...
Graduation date: 2010Functional polymers and proteins at interfaces and surfaces are of fundamental ...
Increasingly used in industrial coatings, polyelectrolytes multilayers (PEMs) are self-assembled sys...
The present study explores the development of mesostructured bioelectrochemical interfaces with accu...
In this work the effects of the self-assembly solvent on the structure and electrochemical behavior ...
Contains fulltext : 10325.pdf (publisher's version ) (Open Access
The strong interaction between a positively charged electroactive polyelectrolyte (polyallylamine de...
High-power density output in enzymatic fuel cells is a key feature to reduce the size of self-powere...
Layer by layer assembly of polyelectrolytes with proteins is a convenient tool for the development o...
Regeneration and reutilization of cofactors remain as the biggest challenge facing the industrial ap...
The cationic polyelectrolyte PVp-S/anionic surfactant SDS and anionic polyelectrolyte P(SPMS-S) S/ca...
We present a new methodology for the generation of discrete molecularly dispersed enzyme− polymer−...
The search for strategies to improve the performance of bioelectrochemical platforms based on supram...
This thesis is focused on the immobilization of a selected biomolecule, Horseradish peroxidase enzym...
The main objective of this PhD thesis was to gain a deep molecular understanding of interactions whi...
High-power density output in enzymatic fuel cells is a key feature to reduce the size of self-powere...
Graduation date: 2010Functional polymers and proteins at interfaces and surfaces are of fundamental ...
Increasingly used in industrial coatings, polyelectrolytes multilayers (PEMs) are self-assembled sys...