We have designed a rigid photocleavable dianthracene-based ligand that reacts with ytterbium as coordination metal ion for the creation of a class of tridimensional light-degradable metal−organic framework (MOF). We demonstrated that we can obtain a high level of control on the disassembly of the MOF formed with this ligand which can be triggered either through light irradiation or temperature increase. The reversible 4π-4π photodimerization is the intrinsic chemical mechanism ruling the ligand and MOF cleavage. In the fields of biology and medicine, MOFs have sparked a strong interest as highly porous vehicles for drug release but have only been explored so far through the passive leakage of their payloads. The designed light-degradable MO...
Metal-Organic Frameworks (MOFs) are porous coordination polymers with the potential to excel in cata...
Minimization of the torsional barrier for phenyl ring flipping in a metal–organic framework (MOF) ba...
Two-dimensional (2D) metal-organic frameworks (MOFs) are fascinating photocatalytic materials becaus...
We have designed a rigid photocleavable dianthracene-based ligand that reacts with ytterbium as coor...
We have designed a rigid photocleavable dianthracene-based ligand that reacts with ytterbium as coor...
In recent years, the international demand for energy has increased rapidly. As a result, the explora...
Utilizing a photolabile ligand as MOF strut can make a framework undergo full or partial decompositi...
Metal-organic frameworks (MOFs) are a class of highly crystalline nanoporous materials that self-ass...
Photocatalytic degradation of pollutants is an effective environment purification strategy. Metal–or...
Metal−organic frameworks, typically built by bridging metal centres with organic linkers, have recen...
The development of visible-light response photocatalysts with a high catalytic performance and long-...
Metal–organic frameworks (MOFs) have witnessed fast-growing development in inorganic chemistry as we...
Metal–organic frameworks (MOFs) are an important family of materials due to the properties that make...
The purpose of this investigation is to find a solution to society’s dependency on fossil fuels sinc...
We describe the newest approach to photodynamic therapy (PDT) using metal-organic frameworks (MOFs) ...
Metal-Organic Frameworks (MOFs) are porous coordination polymers with the potential to excel in cata...
Minimization of the torsional barrier for phenyl ring flipping in a metal–organic framework (MOF) ba...
Two-dimensional (2D) metal-organic frameworks (MOFs) are fascinating photocatalytic materials becaus...
We have designed a rigid photocleavable dianthracene-based ligand that reacts with ytterbium as coor...
We have designed a rigid photocleavable dianthracene-based ligand that reacts with ytterbium as coor...
In recent years, the international demand for energy has increased rapidly. As a result, the explora...
Utilizing a photolabile ligand as MOF strut can make a framework undergo full or partial decompositi...
Metal-organic frameworks (MOFs) are a class of highly crystalline nanoporous materials that self-ass...
Photocatalytic degradation of pollutants is an effective environment purification strategy. Metal–or...
Metal−organic frameworks, typically built by bridging metal centres with organic linkers, have recen...
The development of visible-light response photocatalysts with a high catalytic performance and long-...
Metal–organic frameworks (MOFs) have witnessed fast-growing development in inorganic chemistry as we...
Metal–organic frameworks (MOFs) are an important family of materials due to the properties that make...
The purpose of this investigation is to find a solution to society’s dependency on fossil fuels sinc...
We describe the newest approach to photodynamic therapy (PDT) using metal-organic frameworks (MOFs) ...
Metal-Organic Frameworks (MOFs) are porous coordination polymers with the potential to excel in cata...
Minimization of the torsional barrier for phenyl ring flipping in a metal–organic framework (MOF) ba...
Two-dimensional (2D) metal-organic frameworks (MOFs) are fascinating photocatalytic materials becaus...