Add to ORKGThe purpose of this thesis was two fold: (i) The synthesis and characterization of SF5 containing dienes. (ii) The characterization of hydro/fluorocarbon compounds containing SF5/S02F groups via their 13C NMR spectra. A new SF5CH2CHBrCH2CF=CF2 was prepared and characterized as a precursor to new dielectric polymers. This new adduct was made from the reaction of pentafluorothio bromide with l,l,2-trifluoro-1,4-pentadiene. A SF5-diene was prepared from the reaction of pentafluorothio chloride with acetylene. This reaction involves a radical addition mechanism. The SF5 group is bonded to the carbon atom carrying the most hydrogens. SF5 - dienes are capable of undergoing different reactions, such as polymerization. Fluorocarbon sulfonyl fluorid...
textLiquid-Phase elemental fluorination has been utilized for the synthesis of a wide range of func...
Chapter 1 introduces the discovery of elemental fluorine by H. Moissan and some uses of inorganic fl...
Sulfonyl fluorides, alkyl fluorides and acyl fluorides are common functional groups found in numerou...
Reactions of different alcohols with 2-hydroxy - 1- trifluoromethyl -1,2,2-trifluoroethanesulfonic a...
General Comments. All solvents were dried (using appropriate drying agents), distilled before use an...
This work attempts to shed some light on some of the fundamental chemistry utilized by C-F bonds in ...
The preparation of alkyl, phenyl and pentafluorophenyl derivatives of non-metallic fluorides has bee...
The solvent dependence of the 1H, 13C and 15N NMR spectra of (E)-fluoroacetoxime [(E)-FAO] and of (E...
We report the evaluation of density-functional-theory (DFT) based procedures for predicting 19F NMR ...
The importance of fluorinated organic molecules has grown over the last 50 years, particularly in t...
Over the last several years, fluorine has become an indispensable tool for modulating several proper...
A new method of synthesizing organic fluorides stereospecifically was developed; the elements 'BrF' ...
It is well known that fluorinated molecules play an important role in daily life. For example, organ...
Low-temperature fluorine magnetic resonance spectroscopy has been used to investigate the conformati...
After a general introduction about the properties and preparation of organofluorine compounds (Chapt...
textLiquid-Phase elemental fluorination has been utilized for the synthesis of a wide range of func...
Chapter 1 introduces the discovery of elemental fluorine by H. Moissan and some uses of inorganic fl...
Sulfonyl fluorides, alkyl fluorides and acyl fluorides are common functional groups found in numerou...
Reactions of different alcohols with 2-hydroxy - 1- trifluoromethyl -1,2,2-trifluoroethanesulfonic a...
General Comments. All solvents were dried (using appropriate drying agents), distilled before use an...
This work attempts to shed some light on some of the fundamental chemistry utilized by C-F bonds in ...
The preparation of alkyl, phenyl and pentafluorophenyl derivatives of non-metallic fluorides has bee...
The solvent dependence of the 1H, 13C and 15N NMR spectra of (E)-fluoroacetoxime [(E)-FAO] and of (E...
We report the evaluation of density-functional-theory (DFT) based procedures for predicting 19F NMR ...
The importance of fluorinated organic molecules has grown over the last 50 years, particularly in t...
Over the last several years, fluorine has become an indispensable tool for modulating several proper...
A new method of synthesizing organic fluorides stereospecifically was developed; the elements 'BrF' ...
It is well known that fluorinated molecules play an important role in daily life. For example, organ...
Low-temperature fluorine magnetic resonance spectroscopy has been used to investigate the conformati...
After a general introduction about the properties and preparation of organofluorine compounds (Chapt...
textLiquid-Phase elemental fluorination has been utilized for the synthesis of a wide range of func...
Chapter 1 introduces the discovery of elemental fluorine by H. Moissan and some uses of inorganic fl...
Sulfonyl fluorides, alkyl fluorides and acyl fluorides are common functional groups found in numerou...