Add to ORKGThe problem of characterisation of species present at equilibrium in an electrolyte solution is discussed. Shortcomings of the free energy approach are shown due to inadmissible neglect of entropy changes in complex formation. It is shown that complexes formed with hard ligands are stabilised entirely by entropy changes. Soft or covalent interactions are always characterized by exothermic enthalpy changes
While it is evident that a metal ion in aqueous solution interacts electrostatically with water mole...
The problem of the influence of the solvent on activities of ions is discussed. Some proposals for t...
textThe thermodynamic parameters that govern the molecular recognition phenomena continue to be a s...
The problem of characterisation of species present at equilibrium in an electrolyte solution is disc...
In the last few years, the stability constants for several hundred systems of complex i...
In the last few years, the stability constants for several hundred systems of complex i...
A sensitive calortmeter has been used to measure the heats of formation of complexes in dilute aqueo...
This work describes the accurate measurement of the thermodynamic functions Delta G degree and ...
This work describes the accurate measurement of the thermodynamic functions Delta G degree and ...
A sensitive calortmeter has been used to measure the heats of formation of complexes in dilute aqueo...
Access to the enthalpy and entropy of the formation of metal complexes in solution is essential for ...
The interest in this thesis is the thermodynamic approach to the elucidation of the structures of di...
Abstract. Some approaches which allow to divide thermodynamic functions of the ion associationproces...
Abstract. Some approaches which allow to divide thermodynamic functions of the ion associationproces...
Thesis (M.Sc.)-University of Natal, 1995.The experimental work conducted in this thesis was aimed at...
While it is evident that a metal ion in aqueous solution interacts electrostatically with water mole...
The problem of the influence of the solvent on activities of ions is discussed. Some proposals for t...
textThe thermodynamic parameters that govern the molecular recognition phenomena continue to be a s...
The problem of characterisation of species present at equilibrium in an electrolyte solution is disc...
In the last few years, the stability constants for several hundred systems of complex i...
In the last few years, the stability constants for several hundred systems of complex i...
A sensitive calortmeter has been used to measure the heats of formation of complexes in dilute aqueo...
This work describes the accurate measurement of the thermodynamic functions Delta G degree and ...
This work describes the accurate measurement of the thermodynamic functions Delta G degree and ...
A sensitive calortmeter has been used to measure the heats of formation of complexes in dilute aqueo...
Access to the enthalpy and entropy of the formation of metal complexes in solution is essential for ...
The interest in this thesis is the thermodynamic approach to the elucidation of the structures of di...
Abstract. Some approaches which allow to divide thermodynamic functions of the ion associationproces...
Abstract. Some approaches which allow to divide thermodynamic functions of the ion associationproces...
Thesis (M.Sc.)-University of Natal, 1995.The experimental work conducted in this thesis was aimed at...
While it is evident that a metal ion in aqueous solution interacts electrostatically with water mole...
The problem of the influence of the solvent on activities of ions is discussed. Some proposals for t...
textThe thermodynamic parameters that govern the molecular recognition phenomena continue to be a s...