Stability constants from molecular weigth measurements for the complexes R2Hgbpy (bpy = 2,2\u27-bipyridyl) in carbon tetrachloride and benzene at 25 °C decrease in the order R = CaF5 > > p-HC6F4 = p-MeOC6F4 2\u27: o-HC5F4, and for R2HgOPPha, in the order R = o-HC6F4 > C5F5 > p-HC5F4 = p-MeOC5F4 with higher values in the former solvent. The unexpectedly greater stability of (o-HC5F4)2HgOPPha than (C5F5)2HgOPPha has been related to the structures of the parent mercurials. X-ray photoelectron spectroscopy shows that the acceptor properties of mercury compounds decrease in the order HgCl2 > (C5F5)2Hg = (p-HC5F4)2Hg = (o- HC0F4)2Hg > (p-MeOCoF4)2Hg > (C5Cls)2Hg 2\u27: Ph2Hg > Hg0• A similar study of RHgX compounds suggests that there is reasonab...
International audienceWe present results obtained from high energy-resolution L3-edge XANES spectros...
The aim of this study was to demonstrate the absolute necessity of control experiments for a correct...
Mercury(II) complexes of the type HgX2(H(4)pymtH) (X Cl- Br I-, SCN-, CN-; H(4)pymtH = 3,4,5, 6-tetr...
Stability constants from molecular weigth measurements for the complexes R2Hgbpy (bpy = 2,2\u27-bipy...
Crystalline adducts, Ph2Hg.2L (L = l,lO-phenanthroline, 2,9-dimethyl-1,10-phenanthroline, and 2,4,7,...
Bond dissociation energies (BDEs) of neutral HgX and cationic HgX(+) molecules range from less than ...
Bibliography: p. 130-136.The crystal and molecular structures of phenyl, 2-mercaptopyrimidine mercu...
1. It has been found that mercuric halides react with full esters of phosphorous acid with formation...
Kinetic data are presented for the reaction of alkylchromium complexes (H2O)([14]aneN4)CrR2+ ([14]an...
The X-ray absorption spectra of the reference and model compounds HgCl2, PhHgCl, PhHgOAc and [(PhHg)...
Kinetic data are presented for the reaction of alkylchromium complexes (H2O)([14]aneN(4))CrR2+ ([14]...
International audienceThe thermodynamics and some vibrational properties of hydrogen-bonded complexe...
The complexes, C6F5HgXL, [X = Br or C1; L, = 2,2'-bipyridyl (bipy), 1,lO-phenanthroline (phen), 3,4,...
The effect of solvent on the stabilities of complexes involving a single H-bond or halogen-bond (X-b...
We present results obtained from high energy-resolution L<sub>3</sub>-edge XANES spectroscopy and fi...
International audienceWe present results obtained from high energy-resolution L3-edge XANES spectros...
The aim of this study was to demonstrate the absolute necessity of control experiments for a correct...
Mercury(II) complexes of the type HgX2(H(4)pymtH) (X Cl- Br I-, SCN-, CN-; H(4)pymtH = 3,4,5, 6-tetr...
Stability constants from molecular weigth measurements for the complexes R2Hgbpy (bpy = 2,2\u27-bipy...
Crystalline adducts, Ph2Hg.2L (L = l,lO-phenanthroline, 2,9-dimethyl-1,10-phenanthroline, and 2,4,7,...
Bond dissociation energies (BDEs) of neutral HgX and cationic HgX(+) molecules range from less than ...
Bibliography: p. 130-136.The crystal and molecular structures of phenyl, 2-mercaptopyrimidine mercu...
1. It has been found that mercuric halides react with full esters of phosphorous acid with formation...
Kinetic data are presented for the reaction of alkylchromium complexes (H2O)([14]aneN4)CrR2+ ([14]an...
The X-ray absorption spectra of the reference and model compounds HgCl2, PhHgCl, PhHgOAc and [(PhHg)...
Kinetic data are presented for the reaction of alkylchromium complexes (H2O)([14]aneN(4))CrR2+ ([14]...
International audienceThe thermodynamics and some vibrational properties of hydrogen-bonded complexe...
The complexes, C6F5HgXL, [X = Br or C1; L, = 2,2'-bipyridyl (bipy), 1,lO-phenanthroline (phen), 3,4,...
The effect of solvent on the stabilities of complexes involving a single H-bond or halogen-bond (X-b...
We present results obtained from high energy-resolution L<sub>3</sub>-edge XANES spectroscopy and fi...
International audienceWe present results obtained from high energy-resolution L3-edge XANES spectros...
The aim of this study was to demonstrate the absolute necessity of control experiments for a correct...
Mercury(II) complexes of the type HgX2(H(4)pymtH) (X Cl- Br I-, SCN-, CN-; H(4)pymtH = 3,4,5, 6-tetr...