We report the syntheses, electronic properties, and molecular structures of a series of mono- and dinuclear uranium(IV) hydrochalcogenido complexes supported by the sterically demanding but very flexible, single N-anchored tris(aryloxide) ligand (AdArO)3N)3−. The mononuclear complexes [((AdArO)3N)U(DME)(EH)] (E = S, Se, Te) can be obtained from the reaction of the uranium(III) starting material [((AdArO)3N)UIII(DME)] in DME via reduction of H2E and the elimination of 0.5 equivalents of H2. The dinuclear complexes [{((AdArO)3N)U}2(μ-EH)2] can be obtained by dissolving their mononuclear counterparts in non-coordinating solvents such as benzene. In order to facilitate the work with the highly toxic gases, we created concentrated THF solutions ...
A new robust and high-yielding synthesis of the valuable U<sup>III</sup> synthon [U(BH<sub>4</sub>)...
Investigation of uranium(IV) complexes chelated by a tridentate amine, H3RITA (H3RITA = (MesNHCH2CH2...
The synthesis and characterisation of a rare U(iii) alkyl complex, U[η4-Me2NC(H)C6H5]3, using the di...
We report the syntheses, electronic properties, and molecular structures of a series of polychalcoge...
We here report the synthesis and characterization of a complete series of terminal hydrochalcogenido...
The synthesis of a family of rare uranium(III) alkyl complexes, Tp*2UR (Tp* = hydrotris(3,5-dimethyl...
International audienceHerein, we report the synthesis and characterization of a series of terminal u...
Herein, we report the synthesis and characterization of a series of terminal uranium(IV) hydrosulfid...
The trivalent uranium phenylchalcogenide series, Tp*<sub>2</sub>UEPh (Tp* = hydrotris(3,5-dimethylp...
The chemistry presented in this thesis focuses on three projects involving the organometallic chemis...
The ability of uranium to support multiple oxidation states, achieve various coordination numbers co...
The first use of a dinuclear UIII/UIII complex in the activation of small molecules is reported. The...
Transition metal alkyls play an important role in organometallic chemistry. Thus, exploration of ura...
Known primarily for its single electron chemistry, controlling the electronics at uranium to facilit...
A new dinitrogen adduct of a homoleptic uranium tris(siloxide) complex, [U{OSi(Mes)3}3]2(μ-η2:η2-N2)...
A new robust and high-yielding synthesis of the valuable U<sup>III</sup> synthon [U(BH<sub>4</sub>)...
Investigation of uranium(IV) complexes chelated by a tridentate amine, H3RITA (H3RITA = (MesNHCH2CH2...
The synthesis and characterisation of a rare U(iii) alkyl complex, U[η4-Me2NC(H)C6H5]3, using the di...
We report the syntheses, electronic properties, and molecular structures of a series of polychalcoge...
We here report the synthesis and characterization of a complete series of terminal hydrochalcogenido...
The synthesis of a family of rare uranium(III) alkyl complexes, Tp*2UR (Tp* = hydrotris(3,5-dimethyl...
International audienceHerein, we report the synthesis and characterization of a series of terminal u...
Herein, we report the synthesis and characterization of a series of terminal uranium(IV) hydrosulfid...
The trivalent uranium phenylchalcogenide series, Tp*<sub>2</sub>UEPh (Tp* = hydrotris(3,5-dimethylp...
The chemistry presented in this thesis focuses on three projects involving the organometallic chemis...
The ability of uranium to support multiple oxidation states, achieve various coordination numbers co...
The first use of a dinuclear UIII/UIII complex in the activation of small molecules is reported. The...
Transition metal alkyls play an important role in organometallic chemistry. Thus, exploration of ura...
Known primarily for its single electron chemistry, controlling the electronics at uranium to facilit...
A new dinitrogen adduct of a homoleptic uranium tris(siloxide) complex, [U{OSi(Mes)3}3]2(μ-η2:η2-N2)...
A new robust and high-yielding synthesis of the valuable U<sup>III</sup> synthon [U(BH<sub>4</sub>)...
Investigation of uranium(IV) complexes chelated by a tridentate amine, H3RITA (H3RITA = (MesNHCH2CH2...
The synthesis and characterisation of a rare U(iii) alkyl complex, U[η4-Me2NC(H)C6H5]3, using the di...