Samples with a composition of 40InF 3-20ZnF 2-5MCl- xBaF 2-ySrF 2, where M=Na, Li and x+y=35 mol%, were prepared. The thermal properties related to the Ba/Sr ratio and to the remaining chlorine content in the glasses were studied. Thermal stability is improved with the addition of chlorine. However, chlorine concentration is regulated by the sublimation of indium fluorides which takes place at about 600°C. Indium fluorides arc formed during glass fusion. The mechanisms of chlorine sublimation were studied. © 2005 Akadémiai Kiadó, Budapest
Sulphuryl chlorofluoride has no observable reaction with metals and metal oxides at room temperature...
A series of chloroborosilicate glass having composition (in mol%) (100 -x)(42SiO(2)-30B(2)O(3)-20BaO...
Halide glasses appear to be of potential interest for making ultra-low-loss optical fibres. Fundamen...
International audienceThe solubility, speciation, and local atomic environment of chlorine have been...
Pyrochemical reprocessing of spent nuclear fuels may lead to the generation of chloride containing w...
Abstract Adding fluoride into bioactive glasses leads to fluorapatite formation and a decrease in gl...
Effect of the substitutions of chloride for fluoride on the chemical and physical properties and the...
Their extended transparency in the IR makes them attractive for use as optical fibers for CO laser p...
L'aptitude à la vitrification des mélanges fondus des chlorures et bromures contenant Pb a été étudi...
New halide glasses with considerably lower phonon energy than well-known fluorozirconate glasses hav...
Heavy metal fluoride glasses are promising materials for active optical fibres. The initial systems ...
The aim of this thesis is to understand the chemical behaviour of halogens in silicate melts by expe...
The limits of glass formation of new fluoroindate glass compositions have been determined for the ba...
Crystallization phenomena of fluorochlorozirconate glasses were investigated by means of differentia...
Oxychloride glasses in the ternary system Sb₂O₃ - PbCl₂ - ZnCl₂ have been prepared. The thermal prop...
Sulphuryl chlorofluoride has no observable reaction with metals and metal oxides at room temperature...
A series of chloroborosilicate glass having composition (in mol%) (100 -x)(42SiO(2)-30B(2)O(3)-20BaO...
Halide glasses appear to be of potential interest for making ultra-low-loss optical fibres. Fundamen...
International audienceThe solubility, speciation, and local atomic environment of chlorine have been...
Pyrochemical reprocessing of spent nuclear fuels may lead to the generation of chloride containing w...
Abstract Adding fluoride into bioactive glasses leads to fluorapatite formation and a decrease in gl...
Effect of the substitutions of chloride for fluoride on the chemical and physical properties and the...
Their extended transparency in the IR makes them attractive for use as optical fibers for CO laser p...
L'aptitude à la vitrification des mélanges fondus des chlorures et bromures contenant Pb a été étudi...
New halide glasses with considerably lower phonon energy than well-known fluorozirconate glasses hav...
Heavy metal fluoride glasses are promising materials for active optical fibres. The initial systems ...
The aim of this thesis is to understand the chemical behaviour of halogens in silicate melts by expe...
The limits of glass formation of new fluoroindate glass compositions have been determined for the ba...
Crystallization phenomena of fluorochlorozirconate glasses were investigated by means of differentia...
Oxychloride glasses in the ternary system Sb₂O₃ - PbCl₂ - ZnCl₂ have been prepared. The thermal prop...
Sulphuryl chlorofluoride has no observable reaction with metals and metal oxides at room temperature...
A series of chloroborosilicate glass having composition (in mol%) (100 -x)(42SiO(2)-30B(2)O(3)-20BaO...
Halide glasses appear to be of potential interest for making ultra-low-loss optical fibres. Fundamen...