Synthesis, characterization and thermal behaviour of solid-state tartrates of heavy trivalent lanthanides and yttrium(III)

Ambrozini, B.
Dametto, P. R.
Ionashiro, Massao

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Publication date

September 2011

DOI

10.1007/s10973-011-1370-7

Publisher

Springer

Journal

issn:1388-6150

Abstract

Solid state Ln(2)-L(3) compounds, where Ln stands for heavy trivalent lanthanides (terbium to lutetium) and yttrium, and L is tartrate [(C(4)H(4)O(6))(-2)] have been synthesized. Simultaneous thermogravimetry and differential thermal analysis, differential scanning calorimetry, X-ray powder diffractometry, infrared spectroscopy, elemental analysis and complexometry were used to characterize and to study the thermal behaviour of these compounds. The results provided information concerning the stoichiometry, crystallinity, ligand's denticity, thermal stability and thermal behaviour of these compounds.Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Conselho Naciona...

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Synthesis, characterization and thermal behaviour of solid-state tartrates of heavy trivalent lanthanides and yttrium(III)

Abstract

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Synthesis, characterization and thermal behaviour of solid-state tartrates of heavy trivalent lanthanides and yttrium(III)

Abstract

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