STUDY OF MACROSCOPIC PROPERTIES OF POLYMER CHAINS INTERACTING WITH PENETRABLE SURFACE

IN THE FIRST CHAPTER, THE DISTRIBUTION FUNCTION G(RO, RN, N) FOR IDEAL LINEAR CHAIN INTERACTING WITH PENETRABLE SURFACE BY THE POTENTIAL OF DELTA FUNCTION IS CALCULATED AND IT IS STUDIED. IN THE NEXT FOUR CHAPTERS, THE CONFIGURATION PROPERTIES (CONFIGURATION WEIGHT, DENSITY PROFILE, LINEAR DENSITY, THE SIZE OF THE COIL, THE PARTITION OF MASS AT THE TWO SEMISPACE LEFT AND RIGHT OF THE SURFACE)FOR FIXED AND NOT FIXED LINEAR AND CYCLIC CHAINS ARE STUDIED. UNDER IDENTICAL CONDITIONS THE FREE CYCLIC CHAINS ADSORPED MORE THAN THE LINEAR AT THE SURFACE.IN THE CASE OF LOCALIZED CHAINS, FOR ZO>ZOK(U) THE LINEAR ARE ADSORPED MORE THAN THE CYCLIC WHILE FOR ZOΖΟΚ(U) ΤΑ ΓΡΑΜΜΙΚΑ ΠΡΟΣΡΟΦΩΝΤΑΙ ΠΕΡΙΣΣΟΤΕΡΟ ΑΠΟ ΤΑ ΚΥΚΛΙΚΑ ΕΝΩ ΓΙΑ ΖΟ