Add to ORKGAn approach to synthesize the pentacyclic framework of the polyol diterpenoid ryanodol is reported. The ABC tricycle was constructed by a Co-mediated Pauson–Khand reaction, and both radical and anionic cyclization pathways were developed to form the E-ring. In addition, a reaction sequence involving SeO_2-mediated enone oxidation and hydroxyl-directed oxy-Michael addition was developed to introduce the A-ring oxidation. The feasibility of forming the bridging D-ring by an oxidative dearomatization was established
A concise route toward the syntheses of (−)-drupacine and (+)- and (−)-cephalotaxine has been develo...
A highly efficient, Z-selective ring-closing metathesis system for the formation of macrocycles usin...
Highly thermally stable N-aryl, N-alkyl N-heterocyclic carbene (NHC) ruthenium catalysts were design...
An approach to synthesize the pentacyclic framework of the polyol diterpenoid ryanodol is reported. ...
Ru–cyclic alkyl amino carbene (Ru–CAAC) olefin metathesis catalysts perform extraordinarily in metat...
Ru–cyclic alkyl amino carbene (Ru–CAAC) olefin metathesis catalysts perform extraordinarily in metat...
Ru–cyclic alkyl amino carbene (Ru–CAAC) olefin metathesis catalysts perform extraordinarily in metat...
(+)-Perseanol is an isoryanodane diterpene that is isolated from the tropical shrub Persea indica an...
(+)-Ryanodine is a natural product modulator of ryanodine receptors, important intracellular calcium...
An 18-step synthesis of the antibiotic (+)-pleuromutilin is disclosed. The key steps of the synthesi...
A versatile synthesis of modular ascarosides, a family of signaling molecules from Caenorhabditis el...
Concise and protecting-group-free total syntheses of the marine oxylipins hybridalactone (1) and thr...
A heterobimetallic VFe complex is demonstrated to catalyse hydrazine disproportionation with yields ...
New chiral phosphorus–olefin hybrid ligands derived from the rigid “privileged” l‐proline have been ...
This is the peer-reviewed version of the following article: Advanced Synthesis and Catalysis 358.7 (...
A concise route toward the syntheses of (−)-drupacine and (+)- and (−)-cephalotaxine has been develo...
A highly efficient, Z-selective ring-closing metathesis system for the formation of macrocycles usin...
Highly thermally stable N-aryl, N-alkyl N-heterocyclic carbene (NHC) ruthenium catalysts were design...
An approach to synthesize the pentacyclic framework of the polyol diterpenoid ryanodol is reported. ...
Ru–cyclic alkyl amino carbene (Ru–CAAC) olefin metathesis catalysts perform extraordinarily in metat...
Ru–cyclic alkyl amino carbene (Ru–CAAC) olefin metathesis catalysts perform extraordinarily in metat...
Ru–cyclic alkyl amino carbene (Ru–CAAC) olefin metathesis catalysts perform extraordinarily in metat...
(+)-Perseanol is an isoryanodane diterpene that is isolated from the tropical shrub Persea indica an...
(+)-Ryanodine is a natural product modulator of ryanodine receptors, important intracellular calcium...
An 18-step synthesis of the antibiotic (+)-pleuromutilin is disclosed. The key steps of the synthesi...
A versatile synthesis of modular ascarosides, a family of signaling molecules from Caenorhabditis el...
Concise and protecting-group-free total syntheses of the marine oxylipins hybridalactone (1) and thr...
A heterobimetallic VFe complex is demonstrated to catalyse hydrazine disproportionation with yields ...
New chiral phosphorus–olefin hybrid ligands derived from the rigid “privileged” l‐proline have been ...
This is the peer-reviewed version of the following article: Advanced Synthesis and Catalysis 358.7 (...
A concise route toward the syntheses of (−)-drupacine and (+)- and (−)-cephalotaxine has been develo...
A highly efficient, Z-selective ring-closing metathesis system for the formation of macrocycles usin...
Highly thermally stable N-aryl, N-alkyl N-heterocyclic carbene (NHC) ruthenium catalysts were design...