Supporting a titanium catalyst (FI)TiCl_3 (FI = (N-(5-methyl-3-(1-adamantyl)salicylidene)-2'-(2"-methoxyphenyl) anilinato) onto MAO/silica affords a more active catalytic system for ethylene and 1-olefin trimerization. Cosupporting the (FI)TiCl_3 catalyst with the ethylene polymn. catalyst (CpSiNR)TiCl_2 (CpSiNR = (C5Me4) SiMe_2NCMe_3), either on sep. or the same MAO/silica particles, affords a catalyst system for producing butyl-branched LLDPE from and ethylene-only feed. Recent expts. aimed at defining the mechanism and LLDPE structure will be described
The purpose of this study was to assess the ability of titanium Ti(IV) alkyloxy compounds supported ...
The catalytic synthesis of linear α-olefins from ethylene is a key reaction in the chemical industry...
Activation of a (phenoxy-imine) titanium tri-Me complex with one equiv. of B(C_6F_5)_3 effects the c...
Supporting a titanium catalyst (FI)TiCl_3 (FI = (N-(5-methyl-3-(1-adamantyl)salicylidene)-2'-(2"-met...
Treatment of dry silica with methylaluminoxane (MAO) followed by (FI)TiCl_3 (FI = (N-(5-methyl-3-(1-...
A phenoxy-imine titanium trimerization catalyst and a silylene linked cyclopentadienyl-amido titaniu...
Using combination of ethylene trimerization catalyst and an ethylene polymn. catalyst LLDPEs have be...
Mechanistic studies of homogeneous chromium- and titanium- catalyzed trimerization of ethylene will ...
In the present study, the titanium-catalyzed ethylene trimerization in general, and more specificall...
In the present study, the titanium-catalyzed ethylene trimerization in general, and more specificall...
The selective trimerization of ethylene constitutes a useful source of 1-hexene, an important co-mon...
\u3cp\u3eA silica-supported tandem catalyst system, capable of producing ethylene/1-hexene copolymer...
Treatment of dry silica with methylaluminoxane (MAO) followed by (FI)TiCl<sub>3</sub> (FI = (<i>N</...
The synthesis of low-density polyethylene from ethylene as the only monomer feed has been investigat...
The immobilization of soluble catalyst {Tp(Ms)}TiCl3 (Tp(Ms*)HB(3-mesityl-pyrazolyl)(2)(5-mesityl-py...
The purpose of this study was to assess the ability of titanium Ti(IV) alkyloxy compounds supported ...
The catalytic synthesis of linear α-olefins from ethylene is a key reaction in the chemical industry...
Activation of a (phenoxy-imine) titanium tri-Me complex with one equiv. of B(C_6F_5)_3 effects the c...
Supporting a titanium catalyst (FI)TiCl_3 (FI = (N-(5-methyl-3-(1-adamantyl)salicylidene)-2'-(2"-met...
Treatment of dry silica with methylaluminoxane (MAO) followed by (FI)TiCl_3 (FI = (N-(5-methyl-3-(1-...
A phenoxy-imine titanium trimerization catalyst and a silylene linked cyclopentadienyl-amido titaniu...
Using combination of ethylene trimerization catalyst and an ethylene polymn. catalyst LLDPEs have be...
Mechanistic studies of homogeneous chromium- and titanium- catalyzed trimerization of ethylene will ...
In the present study, the titanium-catalyzed ethylene trimerization in general, and more specificall...
In the present study, the titanium-catalyzed ethylene trimerization in general, and more specificall...
The selective trimerization of ethylene constitutes a useful source of 1-hexene, an important co-mon...
\u3cp\u3eA silica-supported tandem catalyst system, capable of producing ethylene/1-hexene copolymer...
Treatment of dry silica with methylaluminoxane (MAO) followed by (FI)TiCl<sub>3</sub> (FI = (<i>N</...
The synthesis of low-density polyethylene from ethylene as the only monomer feed has been investigat...
The immobilization of soluble catalyst {Tp(Ms)}TiCl3 (Tp(Ms*)HB(3-mesityl-pyrazolyl)(2)(5-mesityl-py...
The purpose of this study was to assess the ability of titanium Ti(IV) alkyloxy compounds supported ...
The catalytic synthesis of linear α-olefins from ethylene is a key reaction in the chemical industry...
Activation of a (phenoxy-imine) titanium tri-Me complex with one equiv. of B(C_6F_5)_3 effects the c...