Electron-transfer processes can play an important role in organometallic chemistry. Herein, we demonstrate that even d^0 organometallic complexes exhibit a rich redox chemistry and present electrochemical, kinetics, and stereochemical studies that establish a general outer-sphere oxidation process for d^0 group 4 metallocene complexes. This oxidation chemistry closely parallels the reported LMCT photochemistry of these complexes
Our group has focused on the organometallic chemistry of rare-earth metals and actinides for a decad...
The chemical and electronic interaction of organometallic species with metal oxide support materials...
The synthesis of transition metal complexes containing redox-active ligands or ligands with redox-ac...
Electron-transfer processes can play an important role in organometallic chemistry. Herein, we demon...
The present contribution will provide an up-to-date overview of novel experimental and theoretical (...
Trinuclear manganese or rhodium complexes of the trindenyl (Td) ligand undergo three separate 1 e–-o...
The kinetics of quenching of [superscript]*Cr(bpy)[subscript]3[superscript]3+ by d[superscript]6 met...
Triplet – triplet absorption of d0 metal complexes was for the first time revealed and studied by me...
Three complexes of cyclotricatechylene (H6ctc), [{PtL}3(μ3-ctc)], have been synthesised: (L = 1,2-bi...
This tutorial explores the major pathways of forming metal–carbon double bonds in high-oxidation-sta...
Six Group 4 metallocene derivatives of group 4 incorporating a redox active benzene-1,2-thiolate lig...
An understanding of the electrochemical properties of organometallic nitrosyl compounds provides a ...
Understanding the effect of redox-inactive metals on the properties of biological and heterogeneous ...
The long-lived ^3(dσ^*pσ) state of binuclear d8 complexes undergoes a variety of reactions. One prom...
From the pioneering work of Taube, 1 electron-transfer reactions can be mechanistically categorized ...
Our group has focused on the organometallic chemistry of rare-earth metals and actinides for a decad...
The chemical and electronic interaction of organometallic species with metal oxide support materials...
The synthesis of transition metal complexes containing redox-active ligands or ligands with redox-ac...
Electron-transfer processes can play an important role in organometallic chemistry. Herein, we demon...
The present contribution will provide an up-to-date overview of novel experimental and theoretical (...
Trinuclear manganese or rhodium complexes of the trindenyl (Td) ligand undergo three separate 1 e–-o...
The kinetics of quenching of [superscript]*Cr(bpy)[subscript]3[superscript]3+ by d[superscript]6 met...
Triplet – triplet absorption of d0 metal complexes was for the first time revealed and studied by me...
Three complexes of cyclotricatechylene (H6ctc), [{PtL}3(μ3-ctc)], have been synthesised: (L = 1,2-bi...
This tutorial explores the major pathways of forming metal–carbon double bonds in high-oxidation-sta...
Six Group 4 metallocene derivatives of group 4 incorporating a redox active benzene-1,2-thiolate lig...
An understanding of the electrochemical properties of organometallic nitrosyl compounds provides a ...
Understanding the effect of redox-inactive metals on the properties of biological and heterogeneous ...
The long-lived ^3(dσ^*pσ) state of binuclear d8 complexes undergoes a variety of reactions. One prom...
From the pioneering work of Taube, 1 electron-transfer reactions can be mechanistically categorized ...
Our group has focused on the organometallic chemistry of rare-earth metals and actinides for a decad...
The chemical and electronic interaction of organometallic species with metal oxide support materials...
The synthesis of transition metal complexes containing redox-active ligands or ligands with redox-ac...