STM conductance spectroscopy and mapping has been used to analyze the impact of molecular adsorption on the quantized electronic structure of individual metal nanoparticles. For this purpose, isophorone and CO2, as prototype molecules for physisorptive and chemisorptive binding, were dosed onto monolayer Au islands grown on MgO thin films. The molecules attach exclusively to the metal-oxide boundary, while the interior of the islands remains pristine. The Au quantum well states are perturbed due to the adsorption process and increase their mutual energy spacing in the CO2 case but move together in isophorone-covered islands. The shifts disclose the nature of the molecule-Au interaction, which relies on electron exchange for the CO2 ligands ...
Recently, it has been reported that the morphology of Au nanoparticles (NPs) affects the catalytic a...
Effective CO<sub>2</sub> capture and reduction can be achieved through a molecular scale understandi...
We report a systematic comparative dispersion-corrected DFT study of single (K, Au, and Pt) atom ads...
STM conductance spectroscopy and mapping has been used to analyze the impact of molecular adsorption...
Gold nano-catalysis reminds me of the alchemists ’ search for the Philosopher’s stone as they tried ...
The self-accelerated adsorption of CO on 1,4-phenylene diisocyanide (PDI)-derived oligomers on Au(11...
Fundamental understanding of support effects and metal–support interaction is critical in heterogene...
Equilibrium structure and electronic transport. properties of a gold nanowire made of a three-atom c...
The density-functional theory is used to investigate the adsorption of Au atoms, Au clusters, and NO...
International audienceThe adsorption of several small molecules on different gold surfaces, Au(001),...
The adsorption behavior of single CO molecules at 4 K bound to Au adatoms on a Ag(001) metal surface...
International audienceThe ligands at the surface of a gold nanoparticle (GNP) have a significant inf...
Gold islands are typically associated with high binding affinity to adsorbates and catalytic activit...
During the last decades the specific manipulation of matter on the (sub-) nanometer scale, also know...
Density functional theory is used to study the effect of increase of the number of Au atom in the ad...
Recently, it has been reported that the morphology of Au nanoparticles (NPs) affects the catalytic a...
Effective CO<sub>2</sub> capture and reduction can be achieved through a molecular scale understandi...
We report a systematic comparative dispersion-corrected DFT study of single (K, Au, and Pt) atom ads...
STM conductance spectroscopy and mapping has been used to analyze the impact of molecular adsorption...
Gold nano-catalysis reminds me of the alchemists ’ search for the Philosopher’s stone as they tried ...
The self-accelerated adsorption of CO on 1,4-phenylene diisocyanide (PDI)-derived oligomers on Au(11...
Fundamental understanding of support effects and metal–support interaction is critical in heterogene...
Equilibrium structure and electronic transport. properties of a gold nanowire made of a three-atom c...
The density-functional theory is used to investigate the adsorption of Au atoms, Au clusters, and NO...
International audienceThe adsorption of several small molecules on different gold surfaces, Au(001),...
The adsorption behavior of single CO molecules at 4 K bound to Au adatoms on a Ag(001) metal surface...
International audienceThe ligands at the surface of a gold nanoparticle (GNP) have a significant inf...
Gold islands are typically associated with high binding affinity to adsorbates and catalytic activit...
During the last decades the specific manipulation of matter on the (sub-) nanometer scale, also know...
Density functional theory is used to study the effect of increase of the number of Au atom in the ad...
Recently, it has been reported that the morphology of Au nanoparticles (NPs) affects the catalytic a...
Effective CO<sub>2</sub> capture and reduction can be achieved through a molecular scale understandi...
We report a systematic comparative dispersion-corrected DFT study of single (K, Au, and Pt) atom ads...