Ca-3[MnN3] (orthorhomb. Cmcm (Nr. 63); a = 842.6(1), b = 1024.7(2), c = 501.4(1) pm; Z = 4) was prepared by reaction of mixtures of Li, Ca and Mn (molar ratio 6:1:1) in tantalum crucibles with nitrogen (1 atm) at 900 degrees C. The crystal structure contains distorted trigonal-planar anions [MnN3](6-) with C-2v-symmetry (Mn - N: 179.4(4) pm and 179.9(5)pm; N-Mn-N: 114.7(1)degrees and 130.6(2)degrees). Ca-3[MnN3] is an isotype of Ca-3[CrN3] and Ca-3[VN3]
The isotypic ternary compounds Ba3[MoN4] and Ba3[WN4] were prepared by reaction of the transition me...
von Richthofen C-G, Stammler A, Bögge H, DeGroot MW, Long JR, Glaser T. Synthesis, Structure, and Ma...
The main goal of the present work was the synthesis of alkaline-earth nitridomanganates (AExMnyNz) w...
Ca-3[MnN3] (orthorhomb. Cmcm (Nr. 63); a = 842.6(1), b = 1024.7(2), c = 501.4(1) pm; Z = 4) was prep...
Sr3[MnN3] (hexag. P 63/m (Nr. 176); a = 764.2(1) pm, c = 529.8(1) pm; Z = 2) and Ba3[MnN3] (hexag. P...
The new ternary nitride Ca6MnN5 has been synthesized by the solid state reaction of Ca3N2 with Mn4N ...
The isotypic phases Ca6GaN5 and Ca6FeN5 (hexagonal, P6(3)/mcm; a = 627.7(3)/623,7(1) pm, c = 1219.8(...
The title compound Ca_3[BN_2]I_3 was obtained from reactions of mixtures of the starting materials C...
Two new calcium nitridomanganates, Ca12[Mn19N23] (P3, a = 11.81341(3) Å, c = 5.58975(2) Å, Z = 1) an...
Unbridged Mn2units are present in the hexanitridodimanganate(IV) ions of the title compound. This is...
The subvalent nitridometalate Ba-6[(Mo1-xTax)N-4]N-0.86 was prepared from mixtures of Mo powder with...
Unverbrückt sind dieMn2-Einheiten in den isolierten Hexanitridodimangant(IV)-Ionen der Titelverbindu...
The synthesis and crystal structure of a mixed valent manganite CaMn3O6, equivalent to Ca2/3Mn2O4, a...
Molybdenum and tungsten powder react readily with alkali and alkaline earth metal nitrides to form n...
Mixed anion oxyhalides with the formula Ca2MnO3X (X = Cl, Br) are synthesized using solid-state reac...
The isotypic ternary compounds Ba3[MoN4] and Ba3[WN4] were prepared by reaction of the transition me...
von Richthofen C-G, Stammler A, Bögge H, DeGroot MW, Long JR, Glaser T. Synthesis, Structure, and Ma...
The main goal of the present work was the synthesis of alkaline-earth nitridomanganates (AExMnyNz) w...
Ca-3[MnN3] (orthorhomb. Cmcm (Nr. 63); a = 842.6(1), b = 1024.7(2), c = 501.4(1) pm; Z = 4) was prep...
Sr3[MnN3] (hexag. P 63/m (Nr. 176); a = 764.2(1) pm, c = 529.8(1) pm; Z = 2) and Ba3[MnN3] (hexag. P...
The new ternary nitride Ca6MnN5 has been synthesized by the solid state reaction of Ca3N2 with Mn4N ...
The isotypic phases Ca6GaN5 and Ca6FeN5 (hexagonal, P6(3)/mcm; a = 627.7(3)/623,7(1) pm, c = 1219.8(...
The title compound Ca_3[BN_2]I_3 was obtained from reactions of mixtures of the starting materials C...
Two new calcium nitridomanganates, Ca12[Mn19N23] (P3, a = 11.81341(3) Å, c = 5.58975(2) Å, Z = 1) an...
Unbridged Mn2units are present in the hexanitridodimanganate(IV) ions of the title compound. This is...
The subvalent nitridometalate Ba-6[(Mo1-xTax)N-4]N-0.86 was prepared from mixtures of Mo powder with...
Unverbrückt sind dieMn2-Einheiten in den isolierten Hexanitridodimangant(IV)-Ionen der Titelverbindu...
The synthesis and crystal structure of a mixed valent manganite CaMn3O6, equivalent to Ca2/3Mn2O4, a...
Molybdenum and tungsten powder react readily with alkali and alkaline earth metal nitrides to form n...
Mixed anion oxyhalides with the formula Ca2MnO3X (X = Cl, Br) are synthesized using solid-state reac...
The isotypic ternary compounds Ba3[MoN4] and Ba3[WN4] were prepared by reaction of the transition me...
von Richthofen C-G, Stammler A, Bögge H, DeGroot MW, Long JR, Glaser T. Synthesis, Structure, and Ma...
The main goal of the present work was the synthesis of alkaline-earth nitridomanganates (AExMnyNz) w...