Outlandish: The spiroketal embedded in spirastrellolide F methyl ester is a daring site for ring closure, yet it has allowed the power of catalytic alkyne scission and activation to be showcased. An improved strategy for the introduction of the labile side chain was also developed
The hydroboration of internal alkynes with pinacolborane as the reagent catalyzed by [Cp*RuCl]4 resu...
An efficient and mild acyl-alkylation of arynes is described. The method is used to synthesize mediu...
A reaction cascade comprising a rhodium-catalyzed C−H activation, a subsequent hydrometalation of an...
Different methods for the formation of the C.25–C.26 bond of spirastrellolide A (1) are evaluated th...
Outlandish: The spiroketal embedded in spirastrellolide F methyl ester is a daring site for ring clo...
Marvel of the sea: A concise and highly convergent total synthesis of the methyl ester of the marine...
A tandem anionic 5-exo-dig cyclization/Claisen rearrangement sequence was used to effect a facile, “...
An expedient method for the C-methylation of alkenylstannanes with formation of trisubstituted alken...
A sequence comprising a ring-closing alkyne metathesis of a propargyl alcohol derivative, followed b...
Although molybdenum alkylidyne complexes such as 1 endowed with triarylsilanolate ligands are excell...
The assigned structure of the dinoflagellate-derived toxin belizentrin was prepared by total synthes...
A concise approach to the algal metabolite 1 is described, which also determines the previously unkn...
The first total synthesis of (+)-aspercyclide C (1) is reported using a kinetically controlled RCM r...
In an attempt to study the ability of the latest generation of alkyne metathesis catalysts to proces...
A largely catalysis based approach to optically active haouamine A (−)-1 is presented, which provide...
The hydroboration of internal alkynes with pinacolborane as the reagent catalyzed by [Cp*RuCl]4 resu...
An efficient and mild acyl-alkylation of arynes is described. The method is used to synthesize mediu...
A reaction cascade comprising a rhodium-catalyzed C−H activation, a subsequent hydrometalation of an...
Different methods for the formation of the C.25–C.26 bond of spirastrellolide A (1) are evaluated th...
Outlandish: The spiroketal embedded in spirastrellolide F methyl ester is a daring site for ring clo...
Marvel of the sea: A concise and highly convergent total synthesis of the methyl ester of the marine...
A tandem anionic 5-exo-dig cyclization/Claisen rearrangement sequence was used to effect a facile, “...
An expedient method for the C-methylation of alkenylstannanes with formation of trisubstituted alken...
A sequence comprising a ring-closing alkyne metathesis of a propargyl alcohol derivative, followed b...
Although molybdenum alkylidyne complexes such as 1 endowed with triarylsilanolate ligands are excell...
The assigned structure of the dinoflagellate-derived toxin belizentrin was prepared by total synthes...
A concise approach to the algal metabolite 1 is described, which also determines the previously unkn...
The first total synthesis of (+)-aspercyclide C (1) is reported using a kinetically controlled RCM r...
In an attempt to study the ability of the latest generation of alkyne metathesis catalysts to proces...
A largely catalysis based approach to optically active haouamine A (−)-1 is presented, which provide...
The hydroboration of internal alkynes with pinacolborane as the reagent catalyzed by [Cp*RuCl]4 resu...
An efficient and mild acyl-alkylation of arynes is described. The method is used to synthesize mediu...
A reaction cascade comprising a rhodium-catalyzed C−H activation, a subsequent hydrometalation of an...
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