No cycle required: The straightforward synthesis of acyclic (amino)(ylide)carbene gold complexes was achieved by reaction of isocyanide gold complexes with phosphorus and arsenic ylides as well as electron-rich olefins. Their ability to form bimetallic species and to act as ligand-transfer reagents has also been established
The discovery of sustainable and scalable synthetic protocols leading to gold-aryl compounds bearing...
Chloromethylgold(I) complexes of phosphine, phosphite, and N-heterocyclic carbene ligands are easily...
Carbophilic Lewis acids can polarize a coordinated π-bond by a slippage mechanism. A series of stabl...
Bisher unbekannte Goldkomplexe mit acyclischen (Amino)(ylid)carben-Liganden wie 1 wurden durch die U...
No cycle required: The straightforward synthesis of acyclic (amino)(ylide)carbene gold complexes was...
Thumbnail image of graphical abstract Accept it! Although the π-acceptor properties of N-heterocycli...
This thesis details the development of a gold-catalysed, ketone-stabilised ylide synthesis and the i...
Title: Synthesis of gold(I) carbene complexes from isocyanoferrocene Author: Petr Harmach Department...
A formal gold-for-chromium transmetalation allowed the gold carbenoid species [Cy3PAuCAr2]NTf2 (11) ...
Being neighborly: The concept of placing two reactive intermediates next to each other to gain stabi...
Gold-ilocks and the 3 mol % catalyst: Bimetallic gold bromides allow the room temperature aminoaryla...
Heterobimetallic complexes derived from carbodiphosphoranes or phosphinidene–carbene adducts are rep...
Very often ligands are anionic or neutral species. Cationic ones are rare, and, when used, the posit...
Gold has emerged as a powerful synthetic tool in the chemist's arsenal. From the early use of inorga...
Carbophilic catalysts that are based on AuI allow a host of different nucleophiles to be added acros...
The discovery of sustainable and scalable synthetic protocols leading to gold-aryl compounds bearing...
Chloromethylgold(I) complexes of phosphine, phosphite, and N-heterocyclic carbene ligands are easily...
Carbophilic Lewis acids can polarize a coordinated π-bond by a slippage mechanism. A series of stabl...
Bisher unbekannte Goldkomplexe mit acyclischen (Amino)(ylid)carben-Liganden wie 1 wurden durch die U...
No cycle required: The straightforward synthesis of acyclic (amino)(ylide)carbene gold complexes was...
Thumbnail image of graphical abstract Accept it! Although the π-acceptor properties of N-heterocycli...
This thesis details the development of a gold-catalysed, ketone-stabilised ylide synthesis and the i...
Title: Synthesis of gold(I) carbene complexes from isocyanoferrocene Author: Petr Harmach Department...
A formal gold-for-chromium transmetalation allowed the gold carbenoid species [Cy3PAuCAr2]NTf2 (11) ...
Being neighborly: The concept of placing two reactive intermediates next to each other to gain stabi...
Gold-ilocks and the 3 mol % catalyst: Bimetallic gold bromides allow the room temperature aminoaryla...
Heterobimetallic complexes derived from carbodiphosphoranes or phosphinidene–carbene adducts are rep...
Very often ligands are anionic or neutral species. Cationic ones are rare, and, when used, the posit...
Gold has emerged as a powerful synthetic tool in the chemist's arsenal. From the early use of inorga...
Carbophilic catalysts that are based on AuI allow a host of different nucleophiles to be added acros...
The discovery of sustainable and scalable synthetic protocols leading to gold-aryl compounds bearing...
Chloromethylgold(I) complexes of phosphine, phosphite, and N-heterocyclic carbene ligands are easily...
Carbophilic Lewis acids can polarize a coordinated π-bond by a slippage mechanism. A series of stabl...