Nano-emulsion based on acrylic acid ester co-polymer derivatives as an efficient pre-tanning agent for buffalo hide

AbstractAcrylic copolymer nanoemulsions were prepared based on methyl methacrylate (MMA) and butyl acrylate (BA). The prepared acrylic copolymer emulsions were characterized using solid content, rheological properties, molecular weight, MFFT and TEM. The prepared polymers were used as pre-tanning of the depickled hide to enhance the physico-mechanical properties of tanned leather. The key parameters which affect exhaustion and fixation of chrome tan as well as shrinkage temperature of the tanned leather were studied and evaluated using SEM, shrinkage temperature and the mechanical properties of the pre-tanned leather. The results showed that, the prepared polymers A & C are the best polymers in improving the physical properties of the treated leather. Furthermore, the shrinkage temperature and the mechanical properties of the tanned leather were improved. In addition, a significant enhancement in the texture of the leather treated by the polymers was noticed as proved by scanning electron microscopy (SEM)