AbstractIt is known that every finite group G can appear as the monodromy group of some Riemann surface of genus ⩾0. The fact that symmetric groups of all orders can appear as monodromy groups of Riemann surfaces of genus zero is a long-standing one. In this paper, a further search has been made in order to determine which finite groups G can and cannot appear as monodromy groups of Riemann surfaces of genus zero. It has been shown, on the one hand, that every alternating group, the simple group PSL(2, 7) and all cyclic and dihedral groups can appear as such monodromy groups by using a right coset representation of each with respect to a particular subgroup. It has been shown, on the other hand, that the quaternion group, the generalized qu...