AbstractThe concept and some basic properties of a twisted Hopf algebra are introduced and investigated. Its unique difference from a Hopf algebra is that the comultiplication δ: A→A⊗A is an algebra homomorphism, not for the componentwise multiplication on A⊗A, but for the twisted multiplication on A⊗A given by Lusztig's rule.Also, it is proved that any object A in Green's category has a twisted Hopf algebra structure, any morphism between objects is a twisted Hopf algebra homomorphism, the antipode s of A is self-adjoint under the Lusztig form (−,−) on A, and the Green polynomials Ma,b(t) share a so-called cyclic-symmetry.As examples, the twisted Ringel–Hall algebras, Ringel's twisted composition algebras, Lusztig's free algebras ′F and no...