The origin and differential accumulation of hydrocarbons in the Cambrian sub-salt dolomite reservoirs in Zhongshen Area were studied based on comprehensive geochemical analysis of core samples, crude oil samples and natural gas samples. Mass spectrometric detection shows the core samples and crude oil samples are characterized by high C28 sterane content, low diasterane content, high gammacerane content and abundant aryl-Isoprenoids, and the associated gas has a low nitrogen content of 0.24%−4.02%, so it is inferred that the oil and gas are derived from Cambrian – Lower Ordovician source rock. The natural gas in the Middle Cambrian has a methane carbon isotope value of −51.4‰ − −44.7‰ and dryness coefficient of 0.65−0.78, representing assoc...